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Explore nonrenewable energy sources, laws of thermodynamics, energy conversion, and efficiency in the US energy sector. Learn about fossil fuels, net energy, EROI, electricity generation, and fuel efficiency.
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Chapter 12 Nonrenewable Energy Resources
We use a variety of energy sources • Energy is the capacity to do work. • Work is when a force acts for a certain distance. • All natural ecosystems must have energy and our modern human civilization must have energy also. In fact, without energy, human civilization ceases to exist.
Two Rules We Cannot Break: the First and Second Laws of Thermodynamics • First Law of Thermodynamics - energy can never be created or lost; it can only be changed from one type to another.
Electrical • Chemical • Mechanical • Heat/thermal • Light • Sound • Kinetic • Potential • Energy transforms to different forms!
Second Law of Thermodynamics - high quality energy always degrades to low quality energy (low temperature heat) and can never be recovered.
Mechanicalenergy(moving,thinking,living) • Chemical • energy • (photosynthesis) • Chemical • energy • (food) • Solar • energy • Waste • Heat • Waste • Heat • Waste • Heat • Waste • Heat • Fig. 2-14, p. 45
What is a BTU? • A British Thermal Unit is the amount of energy need to raise one pound of water one degree Fahrenheit • One BTU = 252 calories • One BTU = 1,055 joules
What is a joule (J)? • It is the force of one newton over one meter • Work needed to make 1 watt of power for 1 second • One joule = 0.238 calories • One joule = 0.0009 BTU’s
What is a calorie? • A calorie is the amount of energy it takes to heat one gram of H2O one degree Celsius • A food Calorie (with a big “C”) is 1000 calories or a single kcal • One calorie = 4.2 joules • One calorie = 0.004 BTU’s
What is a kilowatt-hour? • A kilowatt-hour is using a thousand watts of electricity for one hour. • If you turned on ten 100-watt light bulbs for an hour, you have used up one kilowatt-hour.
We use a variety of energy sources • We use energy in our homes, machinery, and vehicles and to provide comfort and conveniences • Most of our energy comes from the sun • Solar, wind, hydroelectric, photosynthesis, biomass • Fossil fuels = highly combustible substances from the remains of organisms from past geologic ages
Fossil fuels: our dominant source of energy Oil, coal, and natural gas have replaced biomass as our dominant sources of energy • Global consumption is at its highest level ever • The high-energy content of fossil fuels makes them efficient to burn, ship, and store • Electricity = a secondary form of energy that is easy to transfer and apply to a variety of uses
The energy stream of the U.S. is complex The U.S. energy stream is dominated by coal, oil, and natural gas
Nonrenewable Energy • Nonrenewable energy resources- we will use up Earth’s accessible store in decades to centuries • fossil fuels (coal, oil, natural gas) and nuclear fuels.
Energy Use • Commercial energy sources- those that are bought and sold, such as coal, oil and natural gas. • Subsistence energy sources- those gathered by individuals for their own use such as wood, charcoal and animal waste.
It takes energy to make energy • We don’t get energy for free • To harness, extract, process, and deliver energy requires substantial inputs of energy • Drilling for oil requires roads, wells, vehicles, storage tanks, pipes, housing, etc. • All this requires energy • Net energy = the difference between energy returned and energy invested • Net energy = energy returned – energy invested
Energy Return on Energy Invested • Calculation of how much energy we get out of an energy source for every unit of energy expended on its production. • EROI= energy obtained from the fuel energy invested to obtain • Higher ratios mean we receive more energy than we invest • Fossil fuels have high EROI
Electricity Generation • The burning fuel from coal transfers energy to water, which becomes steam. • The kinetic energy contained within the steam is transferred to the blades of a turbine, a large device that resembles a fan. • As the energy in the steam turns the turbine, the shaft in the center of the turbine turns the generator. • This mechanical motion generates energy.
Energy Efficiency • Most coal burning power plants are about 35% efficient. • Combined cycle-a power plant that uses both exhaust gases and steam turbines to generate electricity.
Cogeneration • Cogeneration- using a fuel to generate electricity and to produce heat. • If steam is used for industrial purposes or to heat buildings it is diverted to turn a turbine first. • This improves the efficiency to as high as 90%.
Energy Fuels used for electricity generation in the U.S. in 2012
Fossil fuels are created from fossils • Fossil fuels were formed from organisms that lived 100–500 million years ago • Aerobic decomposition = organic material is broken down and recycled in the presence of air • Anaerobic decomposition = occurs with little or no air • Deep lakes, swamps • Produces fossil fuels
Coal • Coal- a solid fuel formed primarily from the remains of trees, ferns, and other plant materials that were preserved 280-360 million years ago. • Four types of coal ranked from lesser to greater age, exposure to pressure, and energy content. • These four types are: lignite, sub-bituminous, bituminous, and anthracite. • The largest coal reserves are in the United States, Russia, China, and India.
Coal varies in its qualities • Coal varies in water and carbon content and its amount of potential energy • Peat = organic material that is broken down anaerobically • It is wet, near the surface, and not well compressed • Additional pressure, heat, and time turn peat into coal • Lignite = least compressed • Sub-bituminous and bituminous • Anthracite = most compressed and has the most energy
Coal contains impurities • It has sulfur, mercury, arsenic, and other trace metals • The sulfur content depends on whether coal was formed in salt water or freshwater • Coal in the eastern U.S. is high in sulfur because it was formed in marine sediments • Impurities are emitted when coal is burned • Unless pollution control measures are used • Ways to reduce pollution must be found • The Earth holds enough coal to last a few hundred years
Clean coal technologies • Clean coal technologies = technologies, equipment, and approaches to remove chemical contaminants while generating electricity from coal • Scrubbers chemically convert or remove pollutants • Removing sulfur dioxide or nitrogen oxides • Coal that contains lots of water can be dried • Gasification = coal is converted into cleaner synthesis gas (syngas) • Which can be used to turn a gas or steam turbine • These technologies have reduced pollution • But clean coal is still a dirty way to generate power
Can we capture and store carbon? • Even very clean coal still releases greenhouse gases • Carbon capture and carbon storage (sequestration) • CCS captures CO2 emissions • Then converts it to a liquid and stores it underground or in the ocean • The $1.5 billion FutureGen project will design, construct, and operate a coal-burning power plant for electricity while capturing and storing carbon underground • This technology is still too unproven to depend on • It prolongs our dependence on fossil fuels
Coal is mined using two major methods • Strip mining = for deposits near the surface • Heavy machinery removes huge amounts of earth to expose the coal • Subsurface mining = underground deposits are reached by digging tunnels to follow seams (layers) of coal • Mountaintop removal = entire mountaintops are cut off • Environmentally destructive • Common in the Appalachian Mountains
Petroleum • Oil is the world’s most used fuel • Accounts for 35% of world’s energy use • The U.S. uses the most, but China’s and India’s use is increasing • Crude oil (petroleum) = a mixture of hundreds of different types of hydrocarbon molecules • Formed 1.5–3 km (1–2 mi) underground • Dead organic material was buried in marine sediments and transformed by time, heat, and pressure
Not all oil can be extracted • Some oil is so hard to extract, it is not worth the cost • As prices rise, economically recoverable amounts approach technically recoverable amounts • Technology limits what can be extracted • Economics determines how much will be extracted • Proven recoverable reserve = the amount of oil (or any other fossil fuel) that is technically and economically feasible to remove under current conditions
We drill to extract oil • Exploratory drilling = small, deep holes to determine whether extraction should be done • Oil is under pressure and often rises to the surface • Drilling reduces pressure, and oil becomes harder to extract • Primary extraction = the initial drilling and pumping of available oil • Secondary extraction = solvents, water, or steam is used to remove additional oil, but it is expensive • We lack the technology to remove every bit of oil • As prices rise, it becomes economical to reopen a well
Petroleum products have many uses Petroleum products are central to our lives
We may have depleted half our reserves • We have used up 1.1 trillion barrels of oil • Half our reserves • Reserves-to-production ratio (R/P ratio) = the amount of total remaining reserves divided by the annual rate of production (extraction and processing) • At current levels of production (30 billion barrels/year), we have about 40 years of oil left • We will face a crisis not when we run out of oil, but when the rate of production begins to decline
Natural Gas • Natural gas- exists as a component of petroleum in the ground as well as in gaseous deposits separate from petroleum. • Contains 80 to 95 percent methane and 5 to 20 percent ethane, propane, and butane.
Natural gas burns more cleanly than coal • The fastest growing fossil fuel in use today • 25% of global commercial energy consumption • It is versatile and clean-burning • Emits ½ as much CO2 as coal, ⅔ as much as oil • It is used to generate electricity, heat homes, and cook • Liquefied natural gas (LNG) = gas converted to liquid • Can be shipped but there are risks of explosions • Russia leads the world in production • The U.S. leads the world in use • World supplies are projected to last about 60 more years
Natural gas is often wasted • Coalbed methane = from coal seams • Leaks to the atmosphere during mining • Contributes to climate change • In remote oil-drilling areas, natural gas is flared (burned off) • In Alaska, gas captured during oil drilling is being reinjected into the ground for future use • Landfills produce biogenic natural gas • Operators are capturing and selling it
Natural gas extraction becomes challenging • The first gas fields simply required an opening • The gas moved upward • Most remaining fields require pumping by horsehead pumps • Most accessible reserves have been depleted • Fracturing pumps high-pressure salt water into rocks to crack them
Other Fossil Fuels/Synfuels • Oil sands- slow-flowing, viscous deposits of bitumen mixed with sand, water, and clay. • Bitumen (tar or pitch)- a degraded type of petroleum that forms when a petroleum migrates close to the surface, where bacteria metabolize some of the light hydrocarbons and others evaporate.