1 / 19

STATES OF MATTER

STATES OF MATTER. And other stuff Chapter 13.3 & Chapter 14. Kinetic Molecular Theory. States that particles in all forms of matter are in constant motion . Three types of motion: vibration, rotation, and translation

eliora
Download Presentation

STATES OF MATTER

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript

  1. STATES OF MATTER And other stuff Chapter 13.3 & Chapter 14

  2. Kinetic Molecular Theory • States that particles in all forms of matter are in constant motion. • Three types of motion: vibration, rotation, and translation • Explains the fluidity of gases and liquids and how odors move through the air.

  3. KMT is used to describe states of matter based on the energy and motion of the particles

  4. Gas Model High energy No definite shape or volume Compressible Low density Weak intermolecular forces

  5. Threebasic assumptions of kinetic theory as it applies to gases: • 1. Composed of particles (usually molecules or atoms) considered to be small, hard spheres with insignificant volume and far apart – no attractive or repulsive forces among them • 2. Constant random motion with straight paths that change direction after collisions (random walks) av. Speed 1700km/hr

  6. continued • 3. Collisions are elastic – no energy is lost- it is transferred – total KE is constant

  7. Gas Pressure • Result of collision of particles with each other and walls of container • Force per unit of area • Smaller container creates more collisions and greater pressure • No gas, no collisions, no pressure -vacuum

  8. Atmospheric Pressure • Collisions of air molecules with objects • Barometer – instrument used to measure atmospheric pressure • Mercury and aneroid • SI unit pascal (Pa) @ sea level 101.3 kPa • Also, atmospheres, torrs, mm Hg • Must relate to STP OoC and 101.3 kPa

  9. KE and Kelvin Scale • Increase average KE = increase in temp. • All particles do not have the same KE • Some low, medium, & high – mostly med. • No KE = 0 Kelvin = absolute zero • Kelvin temperature is directly proportional to the average KE of particles EX. Helium gas at 200K has twice as much KE as particles at 100K

  10. Liquid Model • Definite volume but no definite shape • Attraction among particles (intermolecular forces) • Particles have enough energy to change position • Motion contributes to average KE • To “escape” (become a gas) must absorb enough energy to overcome intermolecular forces

  11. Liquid to Gas • Evaporation vs Vaporization not boiling boiling • Evaporation is actually a cooling process – particles with highest KE escape thereby decreasing temperature • Vapor pressure is created when a liquid is in a sealed container and particles evaporate forming a gas over liquid

  12. Equilibrium reached when the number of particles vaporizing and condensing is the same • Increase temp. will increase vapor pressure (more particles have minimum KE) • Vapor pressure is measured with a manometer

  13. Boiling Points • Temperature at which vapor pressure of a liquid equals the external pressure. • Why boiling point for water changes with elevation • Normal boiling point = BP at 101.3kPa • Boiling like evaporation is a sort of cooling process (for the liquid)

  14. Solid Model • Definite shape • Definite volume • Particles vibrate around a fixed position • Particles are usually tightly packed in organized patterns (crystals) • Amorphous solids lack internal structure (glass, plastic, rubber)

  15. Melting Points • Temperature at which a solid becomes a liquid • Melting and freezing points are the same – just a matter of whether energy is being absorbed or lost • Note: not all solids melt – some decompose

  16. Phase Diagram • Conditions of temperature and pressure at which a substance exists as solid, liquid, and gas.

  17. GASES • Assumes Volume • of Container • Compressible • SOLIDS • Diffuses Rapidly Takes Shape of Container • Definite Shape Definite Volume • Does Not • Flow Flows Readily • Diffuses • Extremely • Slowly Incompressible • Viscosity • Surface Tension • Diffuses Slowly LIQUIDS

  18. Exothermic – heat (energy) released • Endothermic – heat (energy) absorbed • Is boiling endo or exo? • Is melting endo or exo?

  19. Terms you need to know • Volatile – a substance that vaporizes readily (low intermolecular forces) Diffusion – mixing due to molecular motion Viscosity – resistance to flow Surface tension – tendency of a liquid to maintain a minimum surface area (high intermolecular forces)

More Related