230 likes | 617 Views
Introduction to Chemistry for Allied Health Sciences The Nucleus & Radioactivity Kirk Hunter Chemical Technology Department Texas State Technical College Waco. Nuclear Radiation. Nuclear Radiaition. Originates at the nuclei of atoms Some nuclei are unstable. Radioactive nuclides
E N D
Introduction to Chemistryfor Allied Health SciencesThe Nucleus & Radioactivity Kirk HunterChemical Technology DepartmentTexas State Technical College Waco
Nuclear Radiaition • Originates at the nuclei of atoms • Some nuclei are unstable. • Radioactive nuclides • Parent nuclide changes with time into an atom with a different nucleus, called the daughter nuclide. • Radioactive decay
Radioactive Decay • Unstable nuclei decay by emitting a particle. • Alpha • Beta • Gamma • The nucleus changes to a more stable one through one or more decays.
Half-Life • Time required for one half of a sample of the nuclide to decay. Phosphorus-32 P-32 P-32 P-32 P-32 14 days 14 days 14 days 14 days 64 µg 32 µg 18 µg 8 µg
Radioactive Half-life Half-life – the amount of time required for one-half of a sample of a nuclide to decay. 1 half-life 1 half-life P-32 P-32 P-32 14 days 14 days 64 g 32 g 16 g
Radioactive Half-lives Isotope Half-life C-14 5730 years U-238 4.5*109 years Po-214 1*10-3 seconds N-13 10 minutes P-32 14 days I-131 8.0 days
Types of Radiation • Alpha Particle (α) • Helium nucleus 42He • Beta Particle (β) • Electron 0-1e • Gamma ray (γ) • No measurable mass • Similar to x-rays
Types of Radiation Radiation Symbol Relative Type Mass Alpha Particle (α) 42He Heavy Beta Particle (β) 0-1e Light Gamma ray (γ) 00γ None
Fission Chain Reactions • One neutron from each fission event produces another fission event. • Chain reaction • Process is critical. • Subcritical – not enough neutrons produced to sustain a chain reaction • Supercritical – more neutrons than necessary are produced leading to an uncontrolled chain reaction
Fisson Splitting large nuclei into smaller nuclei with the release of energy.
Nuclear Equations Alpha Decay 21084Po 20682Pb + 42He Beta Decay 146C 0-1e + 147N Gamma Decay 99m43Tc 9943Tc + 00γ
Fusion Combines smaller nuclei into larger ones releasing energy. 21H + 21H 42He + energy http://www.jet.efda.org/pages/content/fusion1.html
Detecting Radiation • Ionizing radiation • Electron is knocked from the atom • Detection • Film (x-ray film) • Geiger-Muller tube / Geiger counter • Scintillation detector • Measure light produced when struck by radiation
Units of Radiation • Curie (Ci) – disintegrations per second (dps) • 1 Ci = 3.7 * 1010 dps • Radiation Absorbed Dose (rad) • Amount of energy • 1 rad = 0.01 J / kg of tissue • Radiation Equivalent Man (rem) • 1 rem = 1 rad * RBE • RBE = relative biological effectiveness
Protection • Shielding • Alpha – low energy, slow • paper • Beta – medium energy, intermediate • lead • Gamma – high energy, very fast • lead
Nuclear Transformations • Conversion of one nucleus into another by bombardment with another. 10n + 23892U 23992U 23993Np + 0-1e 23993Np 23994Pu + 0-1e • Cancer treatment (Co-60) 5927Co + 10n 6027Co + 00γ
Uses of Radionuclides • Food Processing • Improves shelf-life • Kills bacteria and other microorganisms • Reduce insect damage • Retard sprouting in root crops • Poor public perception and acceptance • Nuclear medicine • Xrays • Tracers – blood flow, tumor/cancer detection • I-123, Na-24, Tc-99m, F-18 • Cancer Treatment • Co-60 , I-131