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This lecture focuses on the concepts of enthalpy and entropy and their relationship to phase changes. It covers the heating curves and phase diagrams, explaining the ideas of fusion, vaporization, and condensation. Examples and activities are included to enhance understanding.
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Catalyst • Define endothermic. Give an example. • Define exothermic. Give an example • I cool a glass of water, is this an endothermic process or an exothermic process? End
Today’s Learning Targets • 7.3 – I can draw a phase diagram to describe how pressure and temperature are related and discuss what a triple point is. • 7.4 – I can analyze and draw a heating curve to describe how energy is lost or gained while a substance changes phases. I can identify on the graph the Hfusion and the Hvaporization. • 7.5 – I can describe a reaction using the ideas of enthalpy and entropy.
Today’s Focus Question • How much energy is required to turn my Flamin’ Hot Cheetos into a liquid?
I. Enthalpy (ΔH) • Enthalpyis a measure of the total energy that a system has. • Amount of energy released or absorbed during a process/reaction. • Measured in kilojoules (kJ)
II. Entropy (ΔS) • The universe tends towards disorder. • Entropyis the measurement of the randomness or disorder of a system. • More energy = more disorder • Measure in J/K
I. ΔHfusion and ΔHvaporization • Large amount of energy that is required to change phases • ΔHfusion= Energy to change solid to a liquid. • ΔHvaporization= Energy to change liquid to a gas. • ΔHfreezing= Energy to change liquid to a solid • ΔHcondensation= Energy to change gas to a liquid
II. Heating Curves • Heating curves are graphs of the relationship between temperature and time. • Allow us to identify important values
ΔH of vaporization/condensation ΔH of fusion/freezing
Justify – TPS • Why was the water able to boil at room temperature when we dropped the pressure?
I. Pressure and Temperature • The state of matter of a substance depends on both the temperature and pressure • A phase diagram is a graph temperature, pressure, and phase for a substance
II. Important Points on a Phase Diagram • Triple Point – The temperature and pressure conditions at which the solid, liquid, and gas phases of a substance coexist • Critical Point – The temperature and pressure at which the gas and liquid state become identical and form one phase.
Melting/Fusion Freezing Vaporization Condensation Sublimation Deposition
Class Example • You have a solid at a pressure of 30 atm and -15 oC, if you decrease the pressure at constant temperature, what phases will the substance go through?
Stop and Jot • Atmospheric pressure on Mt. Everest is 0.29 atm. What is the boiling point of water there using the phase diagram below.
Vocab Direct Instruction Assignment • With our group, let’s do some vocab definitions! • Make a power point defining each of these terms: • Enthalpy • Entropy • Δhfusion • Δhvaporization • ΔHfreezing • Make a powerpoint slide for each vocab word with a picture, title, and a definition! • Δhcondensation • Heating curves • phase diagram • Critical Point • Triple Point
Collaborative - Let’s Heat Some Water! • With the table complete the heating curve lab activity. • Heat the ice until it reaches a rolling boil • Show Mr. Astor when you are done
Independent Work Time Complete the phase diagram homework you picked up when you came in.
Learning Log Assessment Rate yourself 1 – 4 on LTs 7.3, 7.4, and 7.5
Exit Slip • What is entropy? • Draw a basic heating curve. Have temperature on the y-axis and heat added on the x-axis. Label solid, liquid, gas, boiling, and freezing. • What is the triple point on the graph below?
Learning Log Assessment Rate yourself 1 – 4 on LTs 7.3, 7.4, and 7.5
Closing Time • Homework 7.2 due Monday/Tuesday • Rough Draft Due Monday/Tuesday • Quiz on Cheetos lab Monday/Tuesday