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Learn about recognizing, evaluating, and controlling workplace hazards to protect workers' health. Discover the hierarchy of controls and key regulations for chemical exposures in oil & gas operations. Understand permissible exposure limits and hazard communication standards.
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Introduction to Industrial Hygiene MODULE 12
What is Industrial Hygiene? Industrial hygiene is the science of anticipating, recognizing, evaluating, and controlling workplace conditions that may cause workers' injury or illness. • Key factors: • Employee exposure to hazards • Control for hazards to protect workers
Steps to Protect Employees • Anticipate potential hazards • Recognize potential hazards • Evaluate exposure and risk • Control exposure and risk • (Not just for health hazards)
Hierarchy of Controls • Engineering controls: Remove hazard • Process change, Chemical substitution • Ventilation, Shielding, Guarding • Requires little or no employee action • Administrative controls: Manage exposure • Worker rotation, Procedures, Training • Trench shoring, Controlled access areas • Requires employee action
Hierarchy of Controls • Personal protective equipment (PPE) • Respirators, Gloves, Boots, Clothing • Fall protection equipment, Hard hats • Requires individual employee action • Last line of defense, behind engineering and administrative controls • Addressed in 29 CFR 1910 Subpart I
Chemical exposures in oil and gas operations • What chemicals are used in oil and gas operations? • How can employees be exposed? • What toxic effects do these chemicals have? • How can employees be protected from these effects?
Toxic and Hazardous Substances 29 CFR Subpart Z
29 CFR Subpart Z • 1910.1000 Air Contaminants: • Includes Z tables: worker exposure limits for specific listed substances • Employee exposure cannot exceed limits • Tables Z-1, Z-2, Z-3 each have their own requirements • PEL = Permissible Exposure Limit
29 CFR Subpart Z • 1910.1001-1096: • Specific regulations for individual substances including: • asbestos (1910.1001); • lead (1910.1025); • bloodborne pathogens (1910.1030), and others • 1910.1200 Hazard Communication
1910.1000(a) - Table Z-1 • Derived from 1968 ACGIH TLVs • American Conference of Governmental Industrial Hygienists • Threshold Limit Values • Levels thought to cause no significant adverse health effects in the majority of the community CHECK
1910.1000(a) - Table Z-1 • Lists common workplace chemicals • Two types of limits: • 8-hour Time Weighted Average (TWA) or • Ceiling (C) limits • Employee exposure shall at no time exceed a ceiling (C) exposure limit
1910.1000(a) - Table Z-1 • 8-hour Time Weighted Averages (TWA) • Employee exposure shall not exceed 8-hour TWA in any 8-hour work shift of a 40-hour work week • Calculations illustrated in (d) • Units: • Parts per million (ppm) • Milligrams per cubic meter (mg/m3)
Substance 8-hr TWA Ceiling Acetone 1000 ppm Carbon monoxide 50 ppm Chlorine 1 ppm Particulates not otherwise regulated (PNOR) 15 mg/M3, Total dust 5 mg/M3, Respirable fraction Table Z-1 Examples Subtitles & Transitions FOR EXAMPLE…
1910.1000(b) - Table Z-2 • Adopted from ANSI standards (American National Standards Institute) • Expanded standards developed for some of the substances found in Z-2, including: • Benzene 1910.1028 • Cadmium 1910.1027 • Formaldehyde 1910.1048 • Methylene chloride 1910.1052
1910.1000(b) - Table Z-2 • Table Z-2 expresses exposure limits as: • 8-hour TWA • Ceiling • Peak • If a substance has both ceiling and peak limits: peak = level never to be exceeded • Exposure levels over the ceiling but under the peak must comply with margin notes in table • TWA must still not be exceeded
1910.1000(b) - Table Z-2 Examples Substance 8-hr TWA Ceiling Peak Notes Benzene 10 ppm 25 ppm 50 ppm 10 min Hydrogen sulfide 20 ppm 50 ppm 10 min Styrene 100 ppm 200 ppm 600 ppm 5 min in any 3 hrs Toluene 200 ppm 300 ppm 500 ppm 10 min
1910.1000(c) - Table Z-3 • 8-hour TWA limits for forms of silica • Adopted from ACGIH TLVs • SiO2 :basic component of sand, granite • Quartz: 2nd most common mineral • Quartz sand (crystalline silica) used to fracture rock formations in wells • Silica in barite, lignite, and bentonite mud additives
Health Effects of Silica • Silicosis • Irreversible but preventable • Most commonly associated with silica dust • Other possible effects: • Lung cancer • Some auto-immune diseases (Scanning electron micrograph by William Jones, Ph.D., compliments of OSHA)
1910.1000(c) - Table Z-3 Substance PEL Crystalline Silica (Respirable fraction) 10mg/m3 % Sio2 + 2 30mg/m3 % Sio2 Amorphous Nuisance dust 15 mg/m3 Respirable dust 5 mg/m3
1910.1000(d) – Computation formulae • Time Weighted Average • E = (C1T1 + C2T2 + …)/total time • Total time used = 8 hours • Example in § 1910.1000(d)(1)(ii) • What about different work schedules? • Varies by chemical • Most chemicals: Worst 8 hours of shift • Lead: adjusted by hours worked • Interpretation – Foulke letter, 1997
1910.1000(d) – Computation formulae • Exposure to Chemical Mixtures • Em = (C1/L1) + (C2/L2) + … + (Cn/Ln) • If Em > 1, employee is overexposed • Assumptions: • Chemicals’ effects are additive • Dose is proportional to C T
1910.1000(e) – To achieve compliance • Administrative or engineering controls first wherever feasible • When those are not feasible for full compliance: protective equipment or other protective measures • Equipment or technical measures must be approved by competent industrial hygienist or qualified person • Respirators: 1910.134
Chemical-Specific Standards • 1910.1001 Asbestos • 1910.1018 Inorganic Arsenic • 1910.1025 Lead • 1910.1026 Chromium (VI) (revised 2006) • 1910.1027 Cadmium • 1910.1028 Benzene • Oil and gas drilling, production, servicing exempt • 1910.1029 Formaldehyde
1910.1020 Access to employee exposure and medical records • Employees, representatives, and OSHA have right of access • Preserved for 30 years, with exceptions • Employee consent for medical records • OSHA access order posted if identifiable • Trade secrets • Employee information
1910.1030 Bloodborne Pathogens • Occupational exposure: • Reasonably anticipated skin, eye, mucous membrane, or parenteral contact • With blood or other potentially infectious materials (OPIM) e.g. certain body fluids, tissues
1910.1096 Ionizing radiation • OSHA standards cover NORM and TENORM • Exposures must be kept within limits even if sources are natural
1910.1201 Retention of DOT markings, placards and labels • Retain markings on packages received until clean enough to remove hazard • Freight container or vehicle retains placards until materials removed enough • Readily visible • Non-bulk packages not to be reshipped: Hazard Communication labels OK
1910.1450 Hazardous chemicals in laboratories • For laboratory use only • Supersedes other standards in Subpart Z – except: • PELs • Prohibition of eye and skin contact • Exposure monitoring and medical surveillance for those over action levels
Protective Measures Other Standards and
General Duty Clause • Recognized hazards may be cited • If there is no PEL: • Consensus or proprietary standards • ANSI, ACGIH, AIHA • Industry Best Practices • Manufacturer Recommendations (MSDS)
Biological Hazards • Potentially infectious material exposure • Contagious diseases e.g. influenza • Vector-borne diseases e.g. Malaria, Lyme disease • Fungi e.g. mold, spores • Toxins e.g. endotoxin • Allergens / sensitizers e.g. pollen, red cedar
Physical and Radiological Hazards • Heat or cold (General Duty Clause) • Vibration (General Duty Clause) • Noise (1910 Subpart G) • Non-ionizing radiation (electromagnetic, light) (1910 Subpart G) • Ionizing radiation
Other Standards • 29 CFR 1926 Subpart D: Occupational Health and Environmental Controls • Construction operations only • API RP 54 • Noise rules allow for 12 hour shifts • Handling drilling fluid chemicals and additives
Protective Measures • How are exposures to health hazards evaluated on your site? • How are they controlled?