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Chapter 2. Atoms, Molecules, and Ions. History. Greeks, BC AD, Alchemy, beginning of element disc. 1600’s Boyle, gases 1800’s more scientists, more laws developed and more elements discovered. Fundamental Chemical Laws. Law of Conservation of Mass
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Chapter 2 Atoms, Molecules, and Ions
History • Greeks, BC • AD, Alchemy, beginning of element disc. • 1600’s Boyle, gases • 1800’s more scientists, more laws developed and more elements discovered
Fundamental Chemical Laws • Law of Conservation of Mass • Mass cannot be created or destroyed but can be changed from one form to another
Law of Definite Proportions • A given compound always contains exactly the same proportions of elements by mass • Take H2O, water. There is no other way to make water. It must always be 2 Hydrogen atoms and one Oxygen atom. • Or 1.008 g H to 16.00 g of O • 1 : 15.87 proportion of H:O by mass
Carbon and Oxygen • CO is always 1 g carbon to 1.33g oxygen (12.0 g 60 16.00g) • CO2 is always 1 g carbon to 2.66 g oxygen
Think of Any Other Compound? • Law of Definite Proportions applies • MgO (24.31 : 16.00 or 1 : 0.6581) • NaCl • KBr • H2O2
Law of Multiple Proportions • When two elements form a series of compounds, the ratio of the masses of the second element that combine with 1 g of the first element can always be reduced to small whole numbers
Example N and O • The amount of N that combines with O is • Compound A, N2O, 2 N : 1 O • Compound B, NO, 1 N : 1 O • Compound C, NO2, 1 N : 2 O • All obey the Law of Definite Proportions
Problems • You react 100 g Compound A with 20 g Compound B to make one product. What is the mass of the product? • A. 10 g B. 100 g C. 120 g D. > 120 g
3 A + B ---- C + D • If you react 4 moles A with 2 moles B what products (moles of C, D) would you get.
What is the difference between the Law of Definite Proportions and the Law of Multiple Proportions?