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Aluminum. Metal of the 21 st Century. Al facts. 8.13 wt.% of the crust Weighs about 1/3 of Cu or Fe Malleable, ductile, easily cast and machined, corrosion resistant Excellent conductor of electricity. History of Discovery. Rubies and Sapphires Corundum 1809 recognized as alumina
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Aluminum Metal of the 21st Century
Al facts • 8.13 wt.% of the crust • Weighs about 1/3 of Cu or Fe • Malleable, ductile, easily cast and machined, corrosion resistant • Excellent conductor of electricity
History of Discovery • Rubies and Sapphires • Corundum • 1809 recognized as alumina • 1825 Al isolated value>>> Au • 1886 Electrolytic process developed • Charles Hall U.S. • Paul Heroult France
History Con’d • 1886 Chemical process of cleaning bauxite –Karl Bayer Austria • 1947 First Al foil
Uses of Al • Packaging • Transportation • Building • Electrical wires • Al compounds • Petroleum industry, refractories, grinding and polishing, synthetic jewels
How is Bauxite formed? • By the weathering of Al rich minerals in the surface environment
Factors that influence weathering • Weatherability of minerals • Climate
Major producers of bauxite • Producers in 2007
Type of Mining • OPEN Pit or STRIP • Remove top soil and store • Break up bauxite into pieces • Clay removed by combination of washing and wet screening
Bauxite Reserves • 1985 21 billion ton • 1990 21.8 billion ton • 1993 23 billion ton • 2006 25 billion ton
Rate of use in 2006 • 177 million tons per year • How long will the reserves last? • Answer: about 141 years
From Bauxite to Al • Beneficiation—Bayer Process • Smelting
Bayer Process • 1888 • From the World Al institute • http://www.world-aluminium.org/production/refining/chemistry.html
Al Smelting • Hall-Heroult • Al Institute
Al Producers • 2001 • 2007
What do we need to make one pound of Al? • 4 # of bauxite ore • Yields • 2# of alumina • Yields • 1# of Al
Environmental Problems • Red mud from Bayer process • F from electrolysis
Your homework • By next Monday I would like you to come up with an estimate of how much it costs to produce a ton of Al----you will need to look up data on the web or in books in the library but for this, usually the web is better
In Class Problem • 1990-2000: recycled about 1.55 million T of Al from old scrap • 2000-2006: drops to about 1.1 million • What does this save the U.S. in electricity??
Data Needed • Production of 1kg of Al uses approximately 15.7 kwh of electricity • There are about 1000 kg in a metric T • The average cost for industrial electricity in the U.S. in 2006 was 6.11 cents/kwh • Takes 5% of the energy to remelt old scrap as it does to produce new Al