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Novel ingredients in Free-From Food manufacturing. Dale Whiteman Technical Development Manager Daymer Ingredients. Who are ?. Food Ingredient distributor established 2003 based in Atherstone on Stour, Warwickshire providing:- stabiliser systems
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Novel ingredients in Free-From Food manufacturing Dale Whiteman Technical Development Manager Daymer Ingredients
Who are ? • Food Ingredient distributor • established 2003 • based in Atherstone on Stour, Warwickshire • providing:- • stabiliser systems • texturiser blends • starches and modified starches • maltodextrins, dextrose & glucose • proteins and emulsifiers • yeast extracts and HVPs • natural savoury flavours • gums and hydrocolloids • dairy ingredients
Free From Ingredients • An ever growing area • Can even lead to nut free “nuts”............ • Limagrain Céréales Ingrédients Nutricorn Nuts • Announced beginning of September • Maize based toasted corn germ • Nutty texture, flavour and aroma
Free From Ingredients • Gluten free • Is Xanthan the only answer? • Dairy Free • Completely dairy free • Lactose free dairy ingredients • Egg free
Gluten free • Function of gluten Different products have different requirements • Bread and cakes • Provides an elastic network controlling air cell size during formation of dough and cooking • On cooking gluten coagulates interacting with other proteins and fat to control toughness and elasticity of structure • Pasta • Elasticity • Al dente texture/chewability
Gluten free bakery • Flour replacement • Typically combinations of corn and potato starch, rice flour, tapioca flour and occasionally include other flours e.g. Buckwheat • Ratios depend on end application • Bread flour • Assorted blends used, all need additional gluten replacers to function • Pasta • Primarily corn flour • Occasionally rice based but can become gummy on cooking • Frying batter • Usually rice flour based
Gluten free bakery • Common options to replace gluten • Xanthan, • Can lead to crumb hardening & gummy mouthfeel • Xanthan alone can control air cell size but volume often restricted • May not be suitable for all • Egg proteins • Currently unstable pricing • Brings another allergen issue • Guar gum • Availability • Cost!!
Gluten free bakery • HPMC (Hydroxypropylmethylcellulose) • Used successfully with corn starch/rice flour blend • Can be tricky to disperse in water • better if premixed with other materials • Typical application rate 2% • Enhances volume • Controls air cell size and distribution • Reduces staling • Current research • Food Hydrocolloids Issue 30 Vol 1 (Jan 2013) p393-400 • Clear demonstration of improvement to commercial gluten free flours using HPMC with or without buckwheat flour
Gluten free bakery • Other cellulose based materials • WellenceTM • Combination of HPMC and CMC specially modified for application • Gives excellent volume increase and air cell control • Relatively low addition rate Without WellenceTM With WellenceTM
Gluten free bakery • Vegetable proteins • Combinations of potato or pea proteins with a blend of corn starch, rice flour and potato starch • More even air cell distribution, enhances volume, improves surface browning With 1.6% Solanic potato protein isolate Control
Gluten free bakery • Vegetable fibre • Insoluble pea fibre • Proposed as a guar substitute • appears to work well with bread and cakes at between 2:1 to 2.5:1substitution level • some cost benefit while maintaining dough viscosity on kneading
Gluten free bakery • Future technology? • Sourdough approach (University College Cork) • Selected lactic acid bacteria and enzymes used to treat wheat flour to produce fully hydrolysed wheat flour with <10ppm gluten • Lactic acid bacteria produce exopolysaccharides i.e. Materials similar to xanthan • Small scale studies seem to indicate no toxicity to coeliac patients however much larger studies are required to confirm safety of this approach
Gluten free Processed meat • Replacement of breadcrumbs and rusk • Used as a binder in sausage and burgers • Found in over 90% of sausages • Usually based on wheat flour • Reduce moisture/fat loss on cooking maintaining juiciness • Usual GF alternatives • Higher fat meat content • Soy flour • Daymer option for low fat gluten free • Blend of potato starches and rice flour
Dairy free • Basic functions of milk proteins • Emulsification • Foam stabilisation • Structuring e.g. cheese • Glazing • Typical alternatives • Soya • Brings another allergen issue • GM free requirements of many customers • Unless high quality/price can bring flavour or colour problems • Egg • Another potential allergen • Pricing currently very unstable
Dairy free emulsification • Newer options for emulsifying • Non dairy proteins including- • Other vegetable proteins (pea, potato, rice) • Generally successful although flavour or colour issues can still be found unless high quality ingredients used • Animal proteins • Gelatin • Fish gelatin
Dairy free • More recent options • Modified starch (Starch sodium octenylsuccinate) E1450 • Some emulsifying capacity • Typical addition rate 0.5-1% • α–Cyclodextrin • Novel Foods approval gained 2008 • Can be effective in a range of applications such as sauces, mayonnaise etc • Optimum effect at high oil levels • Limitations on pH and heat treatment during emulsification
Dairy free - foam • Current usual stabiliser choices • Egg albumen – see earlier issues! • Soy protein isolates • Gelatin and other animal protein • More recent options • Potato and pea proteins • E1450 Starch octenylsuccinate • Emulsifies but may also contribute to aeration • α–Cyclodextrin • Can double overrun on non protein systems • Combinations of cellulose ethers and surface active materials e.g. E481 SSL which is already found in many bread improvers
Dairy free • Analogue cheese • Blends of modified starches • Selected to control firmness and melting properties as well as emulsify fat • Made using standard processed cheese equipment • Other hydrocolloids can be added to improve properties like stretch
Lactose free • Lactose free milk powders • Typical Skim milk powder 50% lactose • Lactose removed by a combination of ultrafiltration and enzyme hydrolysis to <0.1% • Some conversion to glucose & galactose • Overall increase in protein content
Dairy & Egg free - glazes • Milk and egg wash glazes • Seal surface • Add sheen • Enhance browning • Alternatives • Based on dextrins and starches • Addition of vegetable proteins such as potato can enhance finish Control Egg glaze Milk glaze Images from “The Fresh Loaf” www.thefreshloaf.com
Egg free - Emulsification • Similar solutions to dairy free • Egg free mayonnaise dressings • Combinations of modified starches can provide the emulsification and viscosity provided by egg at a range of fat levels
Further Contact • email – info@daymer.com • telephone - +44 (0)1789 450 131 • web – http://www.daymer.com • linkedin – http://www.linkedin.com/company/daymer-ingredients-limited • twitter – http://twitter.com/daymerfood