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Nucleophilic Substitution: Alkylation of α Carbons

Explore detailed mechanisms of nucleophilic substitution, ether synthesis, polyhalogenation, and green principles in organic reactions. Learn about alkylations, enolates, Williamson's ether synthesis, and intramolecular synthesis techniques. Understand epoxide reactions under neutral and basic conditions.

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Nucleophilic Substitution: Alkylation of α Carbons

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  1. Nucleophilic Substitution:Alkylation of α Carbons

  2. Determining Thermodynamic Enolate

  3. Determining Kinetic Enolate

  4. Polyhalogenation of α Carbons under basic conditions

  5. Formation of Ethers

  6. Williamson’s Ether Synthesis • Green Principles Addresses • Less Hazardous Reagents • Safer Solvent • Use of renewable feedstocks

  7. Intramolecular Williamson EtherSyntheses

  8. Reactions of Epoxides under Neutral and Basic Conditions

  9. Reactions of Epoxides under Neutral and Basic Conditions (cont)

  10. Reactions of Epoxides under Neutral and Basic Conditions (cont)

  11. Reactions of Epoxides under Neutral and Basic Conditions (cont)

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