290 likes | 725 Views
Chemical Reaction Engineering Asynchronous Video Series. Chapter 4, Part 3: Pressure Drop in a Packed Bed Reactor H. Scott Fogler, Ph.D. Algorithm for Isothermal Reactor Design. Mole Balance and Design Equation Rate Law Stoichiometry Combine Evaluate. Algorithm.
E N D
Chemical Reaction EngineeringAsynchronous Video Series Chapter 4, Part 3: Pressure Drop in a Packed Bed Reactor H. Scott Fogler, Ph.D.
Algorithm for Isothermal Reactor Design • Mole Balance and Design Equation • Rate Law • Stoichiometry • Combine • Evaluate
Algorithm Analyze the following second order gas phase reaction that occurs isothermally in a PBR:
Algorithm Analyze the following second order gas phase reaction that occurs isothermally in a PBR: Mole Balance: Must use the differential form of the mole balance to separate variables:
Algorithm Analyze the following second order gas phase reaction that occurs isothermally in a PBR: Mole Balance: Must use the differential form of the mole balance to separate variables: Rate Law: Second order in A and irreversible:
Algorithm Analyze the following second order gas phase reaction that occurs isothermally in a PBR: Mole Balance: Must use the differential form of the mole balance to separate variables: Rate Law: Second order in A and irreversible: Stoichiometry: with T=T0
Algorithm Analyze the following second order gas phase reaction that occurs isothermally in a PBR: Mole Balance: Must use the differential form of the mole balance to separate variables: Rate Law: Second order in A and irreversible: Stoichiometry: with T=T0 Combine: Need to find (P/P0) as a function of W (or V if you have a PFR).
Pressure Drop in Packed Bed Reactors Ergun Equation:
Pressure Drop in Packed Bed Reactors Ergun Equation:
Pressure Drop in Packed Bed Reactors Ergun Equation:
Pressure Drop in Packed Bed Reactors Ergun Equation: Let
Pressure Drop in Packed Bed Reactors Ergun Equation: Let Catalyst Weight: Let and
Multiple Reactions and Pressure Drop In terms of conversion:
Multiple Reactions and Pressure Drop In terms of conversion:
Multiple Reactions and Pressure Drop In terms of conversion:
Separate Integrate Analytical Solution
Separate Integrate Analytical Solution For gas phase reactions, as the pressure drop increases, the concentation decreases, resulting in a decreased rate of reaction, hence a lower conversion when compared to a reactor without a pressure drop.
What if… Dpand Ac change? } } Turbulent Laminar
What if… Dpand Ac change? } } Turbulent Laminar
What if… Dpand Ac change? } } Turbulent Laminar
What if… Dpand Ac change? } } Turbulent Laminar