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HIGHER GRADE CHEMISTRY CALCULATIONS

Use D H = -cm D T D H = -4.18 x 0.1 x 10 D H = - 4.18 kJ. ( c is specific heat capacity of water, 4.18 kJ kg -1 o C -1 ) m is mass of water in kg, 0.1 kg D T is change in temperature in o C, 10 o ). HIGHER GRADE CHEMISTRY CALCULATIONS.

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HIGHER GRADE CHEMISTRY CALCULATIONS

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  1. Use DH = -cmDT DH = -4.18 x 0.1 x 10 DH = - 4.18 kJ ( c is specific heat capacity of water, 4.18 kJ kg-1oC-1) m is mass of water in kg, 0.1 kg DT is change in temperature in oC, 10o) HIGHER GRADE CHEMISTRY CALCULATIONS The enthalpy of combustion of a substance is the amount of energy given out when one mole of a substance burns in excess oxygen. Enthalpy of combustion. Worked example 1. 0.19 g of methanol, CH3OH, is burned and the heat energy given out increased the temperature of 100g of water from 22oC to 32oC. Calculate the enthalpy of combustion of methanol. Use proportion to calculate the amount of heat given out when 1 mole, 32g, of methanol burns. 0.19 g  -4.18 kJ So 32 g  32/0.19 x –4.18 = -704 kJ Enthalpy of combustion of methanol is –704 kJ mol-1.

  2. Calculation using enthalpy of combustion Calculations for you to try. 1. 0.25g of ethanol, C2H5OH, was burned and the heat given out raised the temperature of 500 cm3 of water from 20.1oC to 23.4oC. Use DH = -cmDT DH = -4.18 x 0.5 x 3.3 = - 6.897kJ Use proportion to calculate the enthalpy change when 1 mole, 46g, of ethanol burns. 0.25 g  -6.897 kJ So 46g  46/0.25 x -6.897 = -1269 kJ mol-1. 2.0.1 moles of methane was burned and the energy given out raised the temperature of 200cm3 of water from 18oC to 28.6oC. Calculate the enthalpy of combustion of methane. Use DH = -cmDT DH = -4.18 x 0.2 x 10.6 = - 8.86 kJ Use proportion to calculate the enthalpy change when 1 mole of methane burns. 0.1 mol  -8.86 kJ Higher Grade Chemistry So 1mol  1/0..1 x -8.86 = -88.6 kJ mol-1.

  3. Rearrange DH = -cmDT to give DT = DH -cm -11.1 -4.18 x 0.2 DT = = 13.3 oC Calculation using enthalpy of combustion Worked example 2. 0.22g of propane was used to heat 200cm3 of water at 20oC. Use the enthalpy of combustion of propane in the data book to calculate the final temperature of the water. From the data booklet burning 1 mole, 44g, of propane DH = -2220 kJ By proportion burning 0.22 g of propane DH = 0.22/44 x –2220 = - 11.1kJ Higher Grade Chemistry Final water temperature = 20 + 13.3 = 33.3oC

  4. Rearrange DH = -cmDT to give DT = DH -cm -2.27 -4.18 x 0.1 DT = = 5.4 oC Calculation using enthalpy of combustion Calculations for you to try. 1. 0.1g of methanol, CH3OH, was burned and the heat given out used to raise the temperature of 100 cm3 of water at 21oC. Use the enthalpy of combustion of methanol in the data booklet to calculate the final temperature of the water. From the data booklet burning 1 mole, 32g, of methanol DH = -727 kJ By proportion burning 0.1 g of methanol DH = 0..1/32 x –727 = - 2.27 kJ Final water temperature = 21 + 5.4 = 26.4oC Higher Grade Chemistry

  5. Rearrange DH = -cmDT to give DT = DH -cm -11.14 -4.18 x 0.25 DT = = 10.66oC Calculation using enthalpy of combustion Calculations for you to try. 2. 0.2g of methane, CH4, was burned and the heat given out used to raise the temperature of 250 cm3 of water Use the enthalpy of combustion of methane in the data booklet to calculate the temperature rise of the water. From the data booklet burning 1 mole, 16g, of methane DH = -891 kJ By proportion burning 0.2 g of methane. DH = 0..2/16 x –891 = - 11.14 kJ Higher Grade Chemistry

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