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chapter 20 oxidation and reduction a nother way to balance reactions, or another way to look at what happens during a reaction. reactions are an exchange of electrons. some atoms lose, some atoms gain. reduction - is the gaining of electrons ( -)
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chapter 20 oxidation and reduction another way to balance reactions, or another way to look at what happens during a reaction. reactions are an exchange of electrons. some atoms lose, some atoms gain. reduction - is the gaining of electrons ( -) oxidation - is the losing of electrons ( becoming more +) reducing agent- cause another atom to be reduced by donating electrons oxidizing agent- often oxygen, it is the atom that takes electrons and causes another atom to lose them. see pg 156 for rules
see the chart on page 156 for rules about oxidation numbers you need these so you can tell if you are gaining or losing electrons o-2 cl- Mn+3 Na + SO4- try some! KClO3 H2O UF6 MnO4 now try them in a reaction H2 + O2 = H2O
element = o ion = charge oxygen = -2 hydrogen =1 flourine =-1 last element treat as an ion ( or 1st if need be) balance 1st so total is zero if polyatomic ion, balance to charge
try some! Mg +2 KClO3 H2O Cl2 (g) UF6 MnO4 +2 +1, +5, -2 +1, -2 0 +6 -1 +8, -2
+ 3 ways to look at oxidation- remember that originally oxidation always meant where oxygen had been added, like the creation of rust or tarnishing of silver Fe + O2 2Fe2O3 figure oxidation states, see what the job of the oxygen is? so oxidation means to add oxygen it also means to lose electrons it is also the increase of oxidation number!!! it is a good idea to know the chart next page for some common oxidizing and reducing agents!!! try pg 922 1-11
oxidizing agent reduction agent H2, metals, C O2, Halogens F, Cl,I C2O7 -2 MnO4-
quiz over oxidation/reduction numbers For the following reactions, assign oxidation numbers, then list the oxidizing agent 1. KClO3 KCl + O2 2. H2 + I2 HI 3. Cu + AgNO3 Ag + CuNO3
what types of reactions are redox reactions? synthesis and decomp. that should make sense since there are elements either as reactants or products single replacement reactions- when you have an element and a compound, and the element becomes part of the product compound, oxidation states have altered. remember net ionic equations? write it out, seperate the ionic compounds, get rid of everything that doesn't change. that is great for redox, cause you can look at just the exchange of electrons AgNO3 + Cu s CuNO3 + Ags better yet Ag + + Cus Cu+ + Ags
activity series this is a list of metals in order of most reactive to least reactive. it will also help you figure out how a single replacement reaction should occur. good for oxidation reduction cause that is what most are! K Ca react with water Na Mg Al Sn Fe react with acid Ni Sn Pb H2 Cu Hg very unreactive Ag Au
at the same time the list of halogens is just top to bottom of the periodic table. F can replace all I replaces nothing. so can the following occur? Na + Ca(OH)2 Mg + H20? Mg + HCl?