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Bis-Phenol A Alkoxylates

Bis-Phenol A Alkoxylates. BPA Propoxylate. BPA Ethoxylate. EO or PO Distribution. Alkoxylated products always have a Poisson distribution Catalysis and/or reaction temperature can help control distribution. Uniqema’s Process. Sophisticated post-treatment technique Low acid number

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Bis-Phenol A Alkoxylates

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  1. Bis-Phenol A Alkoxylates

  2. BPA Propoxylate

  3. BPA Ethoxylate

  4. EO or PO Distribution • Alkoxylated products always have a Poisson distribution • Catalysis and/or reaction temperature can help control distribution

  5. Uniqema’s Process • Sophisticated post-treatment technique • Low acid number • Gardner color consistently at 1 or below • Very low ion content (Na/K/P) • Tight distribution

  6. Features of BPA Alkoxylates • Hydroxyl termination for use as a resin or a resin intermediate • Aromatic moiety for resistance, adhesion and toughness • Free rotation of methyl groups between aromatic groups for flexibility • Limitless variations in size of EO, PO or EO/PO chains

  7. Benefits of Using BPA Alkoxylates • Corrosion resistance • Chemical and moisture resistance • Flexibility • Toughness/hardness • Improved adhesion • Tg variation to meet final product needs

  8. Uniqema Commercial Products • Ethoxylated BPA • Atlas G 1672 2.2 mole EO • Atlas G 1672/4 2.4 mole EO • Atlas G 1673 3.0 mole EO • Atlas G 1674 BAA 4.0 mole EO • Atlas G 1676 6.0 mole EO • Atlas G 1680 BAA 10.0 mole EO • Atlas G 1682 BAA 12.0 mole EO • Atlas G 1688 BAA 18.5 mole EO • Atlas G 1690 BAA 30.0 mole EO

  9. Uniqema Commercial Products • Propoxylated BPA • Atlas G 1652D 2.0 mole PO • Atlas G 1652 2.2 mole PO • Atlas G 1653 3.0 mole PO • Atlas G 1654 4.0 mole PO • Atlas G 1657 7.0 mole PO • Atlas G 1663BAA 13.0 mole PO • Atlas G 1665 15.0 mole PO

  10. Product Specifications and Production Locations

  11. G-1676 6 mol EO G-1674 4 mol EO G-1673 3 mol EO G-1672 2 mol EO 0,0 1,0 2,0 3,0 4,0 5,0 6,0 7,0 8,0 9,0 10,0 11,0 12,0 13,0 14,0 15,0 16,0 GC-fingerprints of BPA ethoxylates (1)

  12. G-1690BAA 30 mol EO G-1688BAA 18 mol EO G-1682BAA 12 mol EO 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 GC-fingerprints of BPA ethoxylates (2) G-1680BAA 10 mol EO 18 19

  13. Provisional Product Specifications - Asia * : Registered by Alain Bouvy.

  14. 150 100 50 0 0 2 4 6 8 10 12 14 16 GC-fingerprints of BPA (K) ethoxylates (3) G-1688 BAAK 18.8 mol EO G-1680 BAAK 10 mol EO G-1676K 6 mol EO

  15. component G-1672 G-1673 G-1674 G-1676 G-1680 G-1682 BAA G1688 BAA G-1690 BAA BAA > BPA 1.7 2.1 0.8 2.7 1.3 1.1 2.8 0.9 BPA 0.2 1.8 0.1 0.1 0.1 0.1 0.1 0 1 EO 1.2 8.7 2.4 1.3 0.2 0.1 0.1 0.2 2 EO 85 28.7 10.7 5.9 0.9 0.4 0.1 3 EO 9.1 30.7 25.2 9.5 2.1 1.3 4 EO 1.2 15.7 28.3 18.3 3.4 2.1 6 EO 6.9 16.9 19 5.9 4.7 Some components in ethoxylated BPA higher ethoxylates cannot be assigned to peaks unambiguously

  16. GC-fingerprints of BPA-propoxylates (1) G-1654 4 mol PO G-1653 3 mol PO G-1652A 2 mol PO G-1652D 2 mol PO 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24

  17. GC-fingerprints of BPA-propoxylates (2)

  18. Current Uses • Unsaturated polyester resins for fiberglass reinforcement, glass sizing and corrosion resistance • Use PO derivatives from 2.0 to 16.0 • Provide moisture and chemical resistance, adhesion, corrosion resistance • Toner resins • Use EO and PO derivatives 2.0 - 2.2 • Control of Tg (glass transition temperature)

  19. Current Uses • Electodeposition coatings • Use 6.0 EO derivative • Provides hardness for stone resistance and adhesion • Radiation curable monomers • Use EO derivatives from 2.2 to 30 moles • Provide resistances, hardness/flexibility and adhesion

  20. Current Uses • Urethane foam and adhesives • Use various EO and PO derivatives • Provide adhesion to metal

  21. Effect of BPAA in metal coating polyester system • Polyester melamine system • solvent based • building blocks used • Neopentylglycol, Hexanediol, Adipic acid, Isophtalic acid, Terephtalic acid • Hexanediol and Neopentylglycol were used as reference and partially replaced with BPAA

  22. Performance testing • Hardness • König Hardness represents the visco-elastic behaviour of a coating • Buchholz Hardness represents deformation elasticity, i.e. a kind of recoverability (nail test), required for metal coating in particular • Some applications require both properties

  23. Coating properties improvement by using BPAA Skip conditions

  24. Polyester composition Parts by weight!

  25. Polyester composition and differences figures Polyester compositionby weight Differences by weightbetween both ester

  26. Melamine curing • Polyester / melamine ratio: 15 / 1 • Pigment / binder ratio: 12 / 11 • The coating was applied and cured for 1 minute at 230ºC

  27. BPAAUniqema’s business focus • Commitment to & focus on the polymer market • Dedicated Polymer SBU • dedicated sales & marketing, TSS & application people • Polymer di-functional building block experience • Resin synthesis capability • e.g. polyester • Developing application data & knowledge • polyester metal coatings • Plants in more than one region • Europe and USA • Potential to tailor make EO and PO products in both regions

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