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Sulfate Discussion WRAP Meeting – Tucson, AZ January 10/11, 2006. Joe Adlhoch - Air Resource Specialists, Inc. Overview. How much of baseline regional haze in WRAP states is due to sulfate? What are the historical trends in sulfate concentrations?
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Sulfate DiscussionWRAP Meeting – Tucson, AZJanuary 10/11, 2006 Joe Adlhoch - Air Resource Specialists, Inc.
Overview • How much of baseline regional haze in WRAP states is due to sulfate? • What are the historical trends in sulfate concentrations? • What are the contributions of natural and manmade emissions to sulfate? • How are emissions expected to change by 2018? • How is visibility expected to change? • How does this compare with the glidepath? • Selected case studies
Historical Trends in 20% Worst Days: Total and Sulfate Extinction • 16 year trends (1989 – 2004) required 12 complete years of data • 8 year trends (1997 – 2004) required 6 complete years of data • Theil slopes (Mm-1/yr) calculated for all sites with sufficient data • P-values of 0.2 required to identify trend as significant • Changes in monitoring or analytical protocol over the years may affect trends
16-yr Trends 8-yr Trends
Historical Trends, 20% Worst Days Mount Rainier NP 16-yr decrease in Bext 8-yr decrease in SO4
Historical Trends, 20% Worst Days Chiricahua NM 8-yr increase in Bext 8-yr decrease in SO4
Historical Trends, 20% Worst Days Redwood NP 16-yr decrease in Bext 16-yr decrease in SO4
Historical Trends, 20% Worst Days Rocky Mountain NP 8-yr increase in Bext 16-yr decrease in SO4
Total WRAP Region SO2 and NOx Emissions (2002, 2018, and difference)
Gridded Model Results for Annual Average Sulfate Mass • Annual average modeled mass (not 20% worst days) • 2002 and 2018 • Difference (2018 – 2002) • Ratio (2018/2002)
Modeled 2002 SO4 Modeled 2018 SO4
Baseline and Projected 2018 Extinction: 20% Worst Days 2000 – 2004 Baseline Extinction Projected 2018 Extinction
Baseline and Projected 2018 Sulfate Extinction: 20% Worst Days 2000 – 2004 Baseline Sulfate Extinction Projected 2018 Sulfate Extinction
Baseline dv and Projected 2018 dv Reduction: 20% Worst Days 2000 – 2004 Baseline Deciviews Projected 2018 Deciview Reduction
Mount Rainier, WA 2002 IMPROVE Data 2002 Model Results
Glide Path: Mount Rainier, WA Baseline Variability (dv) Baseline Variability by Species
Hells Canyon, OR/ID 2002 IMPROVE Data 2002 Model Results
Glide Path: Hells Canyon, OR/ID Baseline Variability (dv) Baseline Variability by Species