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Hydrogen Gas from the Reaction of Magnesium Metal With Acid. When magnesium metal is treated with acid evolution of hydrogen gas results. Purpose. To observe a chemical reaction between a metal and an acid To measure the amount of hydrogen gas produced. Demonstration.
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Hydrogen Gas from the Reaction of Magnesium Metal With Acid When magnesium metal is treated with acid evolution of hydrogen gas results
Purpose • To observe a chemical reaction between a metal and an acid • To measure the amount of hydrogen gas produced
Demonstration • Hydrogen evolution began as soon as the magnesium metal was added to the water • The hydrogen was less dense than water so it rose through it • The hydrogen gas was able to be collected in the buret
Concepts 1. Single Replacement Reactions 2. Redox Reactions 3. Oxidation Numbers 4. Gases
1. Single Replacement Reactions • A single replacement reaction is of the general form A + BC AC + B In order for a single replacement reaction to occur, A must be more reactive than B in order to combine with C • In this demonstration Mg (s) + HCl (g) MgCl2 (aq)+ H2(g) Since the reaction occurs, we must conclude that magnesium is more reactive than hydrogen
2. Redox Reactions • In a redox reaction, one substance loses electrons while another substance gains electrons • “Redox” is a conventional term which is a combination of the words “reduction” AND “oxidation” • The substance that loses electrons is said to be oxidized and/or the reducing agent • The substance that gains electrons is said to be reduced and/or the oxidizing agent
3. Oxidation Numbers (I) • Oxidation numbers are used to follow electron change and determine what is oxidized and what is reduced during a chemical reaction Mg (s) + 2HCl (g) MgCl2 (aq)+ H2(g) 1+ 2+ 0 0 oxidation reduction Magnesium undergoes oxidation Hydrogen undergoes reduction
Oxidation Numbers (II) • It is important to understand that magnesium gives (loses) its two electrons to the H+ of the acid Mg: Mg 2+ Starting Materials Products H--H 2H+ Magnesium passes its electrons to 2H+ to form H2
4. Gases • The approximate volume of the gas can be calculated as follows • g Mg/Atomic Weight Mg = mol Mg • mol Mg/22.4 mol/L X 1000 = mL hydrogen gas
Conclusions • The reaction in this demonstration was a single replacement reaction AND a redox reaction • The reaction was a quiet reaction • Simple gas law theory was able to predict the approximate volume of gas which formed
Comments • Many metals will react with acid as does magnesium • The hydrogen also contains water vapor and is therefore too wet to burn