C 3 N 6 H 6

+ + 2 HCl C3N6H6 C3N3Cl3 X-Ray Rietveld refinement of C6N9H3•HCl C3N4 graphitic derivatives: High-pressure “soft chemistry” syntheses 1 GPa 525 C C6N9H3 HCl • By combining high-pressure techniques with “soft chemistry” synthetic strategies, we are now able to obtain bulk well-crystallized samples of C3N4 graphitic derivatives. In the above reaction, substituted CN heterocycle molecular precursors are polymerized at 1 GPa and 525 C to form the new layered C6N9H3HCl compound (hexagonal P63/m cell with a = 8.44 A and c = 6.43 A). This material represents the first well-crystallized example of a C-N network material in bulk form. • Similar reaction strategies are now being exploited in an attempt to synthesize the theoretically predicted dense low-compressibility forms of C3N4.

C 3 N 6 H 6

C 3 N 6 H 6

Presentation Transcript

Benzene C 6 H 6

1 H NMR Spectrum of C 5 H 6

p orbitals of C 4 H 6 .

6-3

N C H C

C 6 H 6

6 h

1 Mg, 2 O, and 2 H 2 Mg, 2 O, and 2 H 6 Mg, 6 O, and 6 H 3 Mg, 6 O, and 6 H

N 6+ +H and O 6+ +H charge exchange

Benzene C 6 H 6

N C H C

3 H 2 + N 2  2 N H 3 K c = 9.60 at 600  C

N C H C

Example : C 6 H 6 + Cl 2 --> C 6 H 5 Cl + HCl

Example 2 C 2 H 6  C 2 H 2 + 2H 2 C-C = 347, C-H = 413, C C = 837, H-H = 436

2 C 6 H 6 + 15 O 2 → 12 CO 2 + 6 H 2 O

N C H C

N C H C

C 3 N 6 H 6

C 3 N 6 H 6

Presentation Transcript

Benzene C 6 H 6

1 H NMR Spectrum of C 5 H 6

p orbitals of C 4 H 6 .

6-3

N C H C

C 6 H 6

6 h

1 Mg, 2 O, and 2 H 2 Mg, 2 O, and 2 H 6 Mg, 6 O, and 6 H 3 Mg, 6 O, and 6 H

N 6+ +H and O 6+ +H charge exchange

Benzene C 6 H 6

N C H C

3 H 2 + N 2  2 N H 3 K c = 9.60 at 600  C

N C H C

Example : C 6 H 6 + Cl 2 --&gt; C 6 H 5 Cl + HCl

Example 2 C 2 H 6  C 2 H 2 + 2H 2 C-C = 347, C-H = 413, C C = 837, H-H = 436

2 C 6 H 6 + 15 O 2 → 12 CO 2 + 6 H 2 O

N C H C

N C H C

Example : C 6 H 6 + Cl 2 --> C 6 H 5 Cl + HCl