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What is Arsenic. Natural and abundant element found in soil, air, and waterSolubilityInsoluble in water when in natural formSoluble in water when oxidizedMore toxic in this formMost likely to form compounds with oxygen, chlorine, sulfur, carbon, hydrogen, lead, gold, and iron2 typesInorganic: usually with oxygen, chlorine, or sulfur; most toxic (ex. arsenite)Organic: usually with carbon or hydrogen (ex. di-methyl arsonic acid).
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1. Arsenic Contamination A Great Threat to Subcontinent
Dr. M. A Naeem
Associate Professor Soil Science
Abid Hussain
MSc Hons Agri. Soil Sciences
2. What is Arsenic Natural and abundant element found in soil, air, and water
Solubility
Insoluble in water when in natural form
Soluble in water when oxidized
More toxic in this form
Most likely to form compounds with oxygen, chlorine, sulfur, carbon, hydrogen, lead, gold, and iron
2 types
Inorganic: usually with oxygen, chlorine, or sulfur; most toxic (ex. arsenite)
Organic: usually with carbon or hydrogen (ex. di-methyl arsonic acid)
3. Introduction Arsenic contamination is a growing problem throughout the world
4. Arsenic Occurrence In Asia:
Bangladesh, India, China,
Viet Nam, Cambodia,
Myanmar, Pakistan, Lao
PDR, Nepal …
Elsewhere:
Argentina, Canada,
Hungary, Mexico, Peru,
Nicaragua, Romania, USA
5. Bangladesh Epidemic Problem originated in the 1970s
UNICEF program to provide “safe” water
Arsenic wasn’t a known pollutant at the time
Saved thousands of lives from microbial pathogens, but …
35-77 Million citizens at risk of arsenic poisoning (Out of a pop. of 125 Million)
6. Bangladesh Epidemic The World Health Organization has set a guideline value of 0.01mg/l or 10 ppb
Bangladesh wells range from 0 to 1660 ppb
7. In Pakistan 1978 water sources contained arsenic concentration up to 10 ppb
209 sources remained between 10-50 ppb and 31 sources had arsenic concentration level above 50ppb.
Dadu, Khairpur, Nawabshah and Thatta districts had relatively higher number of water sources with high concentration of arsenic,
Situation could be alarming as other districts might also have arsenic contaminated water sources.
8. Pakistan Cont..
10. Sources of Arsenic Natural sources
Weathering of rocks
Volcanic activity can add
Groundwater in contact with rocks that are high in arsenic
animals and plants make organic arsenic compounds in oceans
Mining/smelting of copper, gold, lead and zinc ores.
11. Sources of Arsenic Cont.. Medical use of arsenic
Wastewater from industries
Wood preservation (greenish CCA pressure treated wood is treated with chromated copper arsenate, an arsenic and chromium containing preservative (70% of world Arsenic pollution)
Pesticide use
Burning materials with arsenic in them
13. Health Risks Arsenic poisoning appears after 10 years of consumption as arsenicosis
Can lead to:
14. Health Risks 10 year old children are developing the arsenicosis
Cancers appear after 20 years
Huge epidemic expected in the near future
16. Treatment Options Treatments are limited
Consumption of only arsenic free water
Zinc, Selenium, and Vitamin A for repair of the skin
Chelation therapy
Not proven to help patients
18. The 8 threats to soil to be monitored(red = priority)
19. Q ???????