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Yew San Hor 1 Department of Chemistry and. Topological Insulators. TAR College, Kuala Lumpur, Malaysia 13 July 2010. J. G. Checkelsky 2 , A. Richardella 2 , J. Seo 2 , P. Roushan 2 , D. Hsieh 2 , Y. Xia 2 , M. Z. Hasan 2 , A. Yazdani 2 , N. P. Ong 2 , and R. J. Cava 1.
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Yew San Hor 1Department of Chemistry and Topological Insulators TAR College, Kuala Lumpur, Malaysia 13 July 2010 J. G. Checkelsky2, A. Richardella2, J. Seo2, P. Roushan2, D. Hsieh2, Y. Xia2, M. Z. Hasan2, A. Yazdani2, N. P. Ong2, and R. J. Cava1 2Department of Physics Princeton University NSF-MRSEC DMR 0819860
Albert Einstein E = mc2
Einstein’s house at Princeton 1935-55 Photo by Ch’ng Ping Choon
Princeton Chemistry Department Spring 2009
Richard Feymann Ch’ng Ping Choon
Princeton Condensed Matter Group Physics & Chemistry NSF-MRSEC
Chemistry Matthias Prize for New Superconducting Materials 1996 Robert J. Cava
Physics • Director of NSF MRSEC DMR 081986 • 2006 Kamerlingh Onnes Prize (For research accomplishments in HTc superconductor) Nai Phuan Ong
Zahid Hasan Yew San Hor David Hsieh Bob Cava
t = 10-32 sec t ~ 300,000years Relativistic energy E2 = p2c2 + m2c4 Elementary particles E k Dirac equation (μ∂μ + mc)ψ = 0 E ~ k
Non-relativistic energy t ~ 300,000years Schroedinger Equation: E Condensed Matter k E~k2
t ~ 1.5 × 1010 years New condensed matter phase
Topological Insulators source: spie.org
Bulk Insulator L E s BCB k BVB Strong Spin-Orbit Coupling E~k2 Topological Insulators
E Bulk Insulator SCB E~k k L E Surface Conductor s SVB BCB k BVB Strong Spin-Orbit Coupling E~k2 Topological Insulators
…is a band insulator which is characterized by a topological number and has Dirac-like excitations at its boundaries. Topological Insulators
Topology …is the mathematical study of the spatial properties that are preserved under continuous deformations of objects, for examples, twisting and stretching, but no tearing or gluing.
Topology = sphere ellipsoid
Topology =
Topology in condensed matter electronic phases… Electron spin property plays an important role. Example: B A
Insulator material does not conduct electric current 1.Band Insulator (valence band completely filled). 2. Peierls Insulator (lattice deformation). 3. Mott Insulator (Coulomb repulsion). 4. Anderson Insulator (impurity scattering). A new class of insulator Topological Insulator
Topological Insulators E Bulk Conduction Band Gapped bulk insulator • Bulk band insulators. E ~ k2 k Bulk Valence Band • Gapless Dirac excitations at its boundaries. E Surface Conduction Band Gapless surface state E ~ k k Ingredients: Strong spin-orbit coupling. Time reversal symmetry. Surface Valence Band
2D electron gas No boundary
Applied B-field out of plane When boundary is created, interface with vacuum state → Edge state. Electron charge → Quantum Hall effect
Insulator Conducting edge state Vacuum …but this breaks Time Reversal Symmetry. Electron charge → Quantum Hall effect
Conducting edge state (Reversed with T operator) Broken Time Reversal Symmetry Electron charge → Quantum Hall effect
“charge” Electron charge → Quantum Hall effect
Classical Hall Effect Quantum Hall Effect (Klaus von Klitzing, 1980) Quantization of Hall conductance xy = ie2/h Lorentz Force F= -e x B h/e2 = 25812.807 Hall conductance xy = -ne/B 1985 Nobel Prize in Physics
Fractional Quantum Hall Effect (discovered in 1982) Daniel Tsui Horst Stormer 1998 Nobel Prize in Physics Quantization of Hall conductance xy = ie2/h Robert Laughlin i = 1/3, 1/5, 5/2, 12/5 ..
Devices utilize electron charge property: Semiconductor Transistor, AT&T Bell Labs (1947). Single Crystal Germanium (1952). Single Crystal Silicon (1954). IC device, Texas Instrument (1958). IC Product, Fairchild Camera (1961). Microprocessor, Intel (1971). Personal Computer (1975).
Semiconductor crisis Gorden Moore (co-founder of Intel 1964): Number of transistors doubled every 12 months while price unchanged. In 1980s, number of transistors doubled every 18 months. *Size limit *Heat dissipation
New materials utilize electron spin property:Topological Insulators
Topological Insulators Spintronic devices - apply electron spin property. Quantum computer - apply quantum mechanical phenomena. - use qubit (quantum bit) instead of bit.
Topological Insulator is also important for… 1. Quantum Spin Hall Effect. 2. The search of Majorana fermion. 3. Axion electrodynamic study. 4. Magnetic monopole.
3D Topological Insulator Strong spin-orbit coupling L L s s L s L s L s L s Bulk insulator No boundary Large atomic number → Large orbital moment, L
3D Topological Insulator L L s s L s Bulk insulator Strong spin-orbit coupling
3D Topological Insulator Etrap Etrap k x Etrap ~ B s k2 k1 s L s Bulk insulator Strong spin-orbit coupling
3D Topological Insulator Etrap Etrap s -k2 -k1 s When T-operator is applied… Time Reversal Symmetry Invariant! Bulk insulator s Strong spin-orbit coupling L