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Exploration of Earth-Abundant Transition Metals (Fe, Co,

Exploration of Earth-Abundant Transition Metals (Fe, Co, Ni) as Catalysts in Unreactive Chemical Bond Activations. Bo Su, Zhi-Chao Cao, and Zhang-Jie Shi. Reporter: Li Li Superbisor: Yong Huang 2015-1 2 - 29. Acc. Chem. Res. 2015 , 48 , 886. Concept. Inert chemical bond activation logic.

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Exploration of Earth-Abundant Transition Metals (Fe, Co,

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  1. Exploration of Earth-Abundant Transition Metals (Fe, Co, Ni) asCatalysts in Unreactive Chemical Bond Activations Bo Su, Zhi-Chao Cao, and Zhang-Jie Shi Reporter: Li Li Superbisor: Yong Huang 2015-12-29 Acc. Chem. Res.2015, 48, 886

  2. Concept

  3. Inert chemical bond activation logic

  4. Table Fe catalysis Fe-catalyzed C-O activation Co catalysis Co-catalyzed C-O activation Ni catalysis Ni-catalyzed eheric C-O activation Ni-catalyzed esteric C-O activation Ni-catalyzed C-O activation of aryl/alkenyl carbamates. Ni-Catalyzed C-O bond activation of phenolates Ni-Catalyzed C-O activation of benzylic alcohols

  5. Fe catalysis Fe-catalyzed C-O activation J. Am. Chem. Soc.2009,131, 14656-14657.

  6. Fe catalysis Fe-catalyzed C-O activation Chem. Commun. 2013,49, 7794-7796.

  7. Fe catalysis

  8. Co catalysis C-O activation J. Chem. Soc. D,1970, 847 Eur. J.Org. Chem.2005, 2005, 989 J. Am. Chem. Soc.2012, 134,14638

  9. Ni catalysis C-O activation J. Am. Chem. Soc. 2008, 130, 3268 Chem. Commun.2008, 1437

  10. Ni catalysis Rational Design of Selective C-O Activation of Carboxylate Chem. Lett. 1976, 1091

  11. Ni catalysis Selective C−O Activation of ArylCarboxylates Angew. Chem., Int. Ed.2008, 47, 10124 J. Am. Chem. Soc.2008, 130, 14468 Chem.Eur. J. 2010, 16, 5844

  12. Ni catalysis Tentative Mechanism of the Ni-Catalyzed SelectiveC-O Activation of Aryl Carboxylates

  13. Ni catalysis sp3 C-O Activation of α-PivaloxylKetones Chem. Commun.2011, 47, 7224

  14. Ni catalysis Proposed Mechanism of the Ni-Catalyzed sp3 C-O Activation of α-Pivaloxyl Ketones

  15. Ni catalysis Selective sp3 C-O Activation of Aryl/Alkenyl Carbamates Org. Lett. 2010, 12, 884

  16. Ni catalysis C-O Activation of MagnesiumNaphtholates Angew. Chem. Int.Ed.2010, 49, 4566

  17. Ni catalysis Rational Design of the New Mutual ActivationConcept

  18. Ni catalysis C-O Activation of SodiumNaphtholates Angew.Chem.Int. Ed.2011, 50, 7097

  19. Ni catalysis Possible Role of Et3B in the Mutual Activation.

  20. Ni catalysis sp3 C-O Bond Activation of BenzylicAlcohols J. Am. Chem. Soc.2012, 134,14638

  21. Summary Fe-, Co-, and Ni-catalyzed C-O acivation Unveiling the relationship between their structures and their reactivity are highly needed Earth abundanttransition-metal catalysis VS late transition-metal AliphaticC-Htransformations Designing new ligand for different condition

  22. A H K N T S

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