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Solids, Liquids & Gases. Standards. Be able to identify the four states of matter based on volume, shape, and particle arrangement On a state of change graph, be able to identify heat of fusion and heat of vaporization Be able to calculate density, given mass and volume. What is matter?
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Standards • Be able to identify the four states of matter based on volume, shape, and particle arrangement • On a state of change graph, be able to identify heat of fusion and heat of vaporization • Be able to calculate density, given mass and volume
What is matter? Anything that has mass and takes up space
Kinetic Theory I. Kinetic theory – explains how particles in matter behave.
A. Based on a few assumptions • All matter is composed of small particles • Particles are in constant, random motion • Particles collide with each other and walls of their containers
B. Thermal energy – total energy of a material’s particles; causes particles to vibrate in place. Lower temperature means less thermal energy which means particles move slower
C. Average kinetic energy – temperature of the substance, or how fast the particles are moving; the higher the temp, the faster the movement.
D. States of Matter Ex. Sporting event
1. Solid state –particles are closely packed together in a specific type of geometric arrangement.
Solid State a.Strong attraction between particles b.Definite shape c.Definite volume d.Particlesvibrate in place
2. Liquid state – a solid begins to liquefy at the melting point as the particles gain enough energy to overcome their ordered arrangement
Liquid State • Attractive forces strong enough to keep particles clinging together • Definite volume • No definite shape
Heat of fusion - energy required to reach the melting point. Melting point – the temperature at which a solid begins to liquefy.
3. Gaseous state – a liquid’s particles have enough energy to escape the attractive forces of the other particles in the liquid
Gases • No fixed volume • No fixed shape • Attractive forces are overcome between molecules
E. Vaporization • Process of particles entering the gas state is known as vaporization • Vaporization occurs in two ways: 1. evaporation 2. boiling
1. Evaporation • Evaporation – vaporization that occurs at the surface of a liquid • Evaporation occurs at temperatures below boiling point • Boiling point – the temperature at which a liquid begins to vaporize. • Particles have to have enough kinetic energy to evaporate
2. Boiling – occurs throughout the liquid. • At the boiling point, the pressure of a liquid’s vapor is equal to the pressure of the atmosphere, and the liquid becomes a gas • Heat of vaporization is the energy required for a liquid at boiling point to change to a gas
Heating Curves • Heating curve of a liquid shows the temperature change of water as thermal energy or heat is added
F. Diffusion • Diffusion – the spreading of particles throughout a given volume until they are uniformly distributed. • Can occur in solids and liquids, but mostly in gases • Ex. Air freshener
4. Plasma – state of matter consisting of high-temp gas with balanced (+) and (-) charged particles.
Why are there lines/seams in concrete bridges, driveways, or sidewalks?
II. Thermal expansion – increase in the size of a substance when the temperature increases.
1. The size of a substance will then decrease when the temp decreases and vice versa. • Bimetallic strip
2. Expansion & contraction occur in most solids, liquids, and gases
3. Exceptions A. Water expands as it becomes a solid because it has a polar bond ex. potholes
When freezing, water molecules arrange themselves based on the charge of molecules. • This leaves empty spaces in the molecule. • Empty spaces are larger in ice than liquid
Other exceptions: B. Amorphous solids – lack the tightly ordered structure found in crystals. • Do not have definite temp at which they change from solid to liquid • Ex. Glass, plastic
C. Liquid crystals do not lose their ordered arrangement completely upon melting • Used in liquid crystal displays in watches, clocks, calculators & some notebook computers
Questions • How can a frozen, solid ice cube have motion? • Yes it can have motion. It has motion by vibrating in place. • What causes the particles to have motion? • Thermal energy causes them to vibrate. • What happens to the thermal energy when temperature is lowered? As a result do the particles move faster or slower? • When temperature is lowered, the particles have less thermal energy, and vibrate more slowly.
Questions • Which will move slower? • A) molecules of frozen water at 0C • B) molecules of water at 100C • Which has lower average kinetic energy? • “A” has lower average kinetic energy because it is moving slower • How are kinetic energy and temperature related? • Temperature is the average kinetic energy of the molecules of a substance
MORE Questions • What is heat of fusion? • Amount of energy needed to go from solid to liquid phase • Why do liquids flow? • Particles have gained enough kinetic energy to partially escape the attractive forces in the solid • How does external pressure affect the boiling point of a liquid? • The higher the atmospheric pressure, the higher the boiling point
Even MORE Questions • How do liquids become a gas? • Particles in liquid are constantly moving. Some are moving faster and have more kinetic energy. Particles move fast enough to break attractive forces of other particles and enter gas state.