220 likes | 229 Views
National 5 Supported Study. Acids and Bases. Mandatory Areas. Acids and bases Dissociation of water into hydrogen and hydroxide ions. pH is related to the concentration of hydrogen and hydroxide ions in pure water, acids and alkalis. Neutralisation Titrations. Water.
E N D
National 5 Supported Study Acids and Bases
Mandatory Areas • Acids and bases • Dissociation of water into hydrogen and hydroxide ions. • pH is related to the concentration of hydrogen and hydroxide ions in pure water, acids and alkalis. • Neutralisation • Titrations
Water • Water contains hydrogen and hydroxide ions. • H2O(l) H+(aq) + OH-(aq) 99% 1% • Hence why water is covalent but conducts electricity • A small percentage of water actually exists as Hydrogen and Hydroxide Ions
pH • In pure water • [H+] = [OH-] • The concentration of hydrogen ions equals the concentration of hydroxide ions • Hence why water has a pH of 7
pH • In ACIDIC solutions • [H+] > [OH-] • The concentration of hydrogen ions is greater than the concentration of hydroxide ions
Acids • pH less than 7 • Contain more Hydrogen ions (H+) than hydroxide ions (OH-) • When diluted • Concentration of H+ ions decreases • pH INCREASES towards 7
pH • In ALKALINE solutions • [H+] < [OH-] • The concentration of hydroxide ions is greater than the concentration of hydrogen ions.
Alkaline Solutions • pH greater than 7 • Contain more hydroxide ions (OH-) than Hydrogen ions (H+) • When diluted • Concentration of OH- ions decreases • pH DECREASES towards 7
Neutralisation • A neutralisation reaction is where an acid is neutralised by a base resulting in a neutral solution. • A base is a substance which can neutralise an acid • Metal Oxides e.g. MgO CaO • Metal Carbonates e.g. CaCO3, BaCO3 • Metal Hydroxides e.g. NaOH, Mg(OH)2
KEY NEUTRALISATION REACTIONS Acid + Metal Salt + Water Hydroxide Acid + Metal Oxide Salt + Water • Acid + Metal Salt + Water + CO2 carbonate
Naming Salts • Ending comes from the Acid • Hydrochloric = Chloride salt • Nitric = Nitrate Salt • Sulphuric = Sulphate Salt • Beginning comes from the Metal part of base
Name that salt! • Lithium hydroxide + Hydrochloric acid • Calcium hydroxide + sulphuric acid • Potassium hydroxide + nitric acid • Ammonium hydroxide + hydrochloric acid • Sodium hydroxide + carbonic acid
Answers! • Lithium chloride + water • Calcium sulphate + water • Potassium nitrate + water • Ammonium chloride + water • Sodium carbonate + water
Titration Acid will be measured in burette Alkali in pipette (10cm3)
Titration Question • If 25cm3 of HCl is neutralised by 50cm3 NaOH (0.2mol/l), what is the concentration of the acid? HCl + NaOH NaCl + H2O
Spectator Ions • They watch the reaction and do not take part • They are exactly the same on the reactant and product side. • Same state, same number, same charge
Precipitation Reactions • Precipitate = a solid • Precipitation reaction is when two solutions (aq) are reacted together and an insoluble product is formed – a solid (s) • Easily identified by state symbols • (aq) + (aq) (s) + (aq)