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Background. All life requires Nitrogen Proteins Amino Acids Nucleic Acid 79% of the air is N2 This form cannot be used by most organisms Organisms need a fixed form (incorporated into a compound). Usable Nitrogen. Plants secure Nitrogen in a fixed form nitrate ions (NO3−)
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Background • All life requires Nitrogen • Proteins • Amino Acids • Nucleic Acid • 79% of the air is N2 • This form cannot be used by most organisms • Organisms need a fixed form (incorporated into a compound)
Usable Nitrogen • Plants secure Nitrogen in a fixed form • nitrate ions (NO3−) • ammonia (NH4+) • Assimilation- Animals secure Nitrogen from plants and other animals that have eaten plants in organic material
Nitrogen Fixation • The breaking apart of N2 so that the atoms can combine with other atoms • 3 processes: • 1) atmospheric fixation • 2) biological fixation • 3) industrial fixation
Atmospheric Fixation • Energy in lighting breaks apart N2 molecule and N combines with Oxygen in the air • Nitrates (NO3-) forms in rainwater and falls to the earth • 5-8% of the total nitrogen fixed
Biological Fixation • Some species of bacteria can fix atmospheric N2 into ammonium (NH4) • Can be free living bacteria or symbiotically associated with plants • Legumes form a symbiotic relationship with bacteria from the genus: Rhizobium
Industrial Fixation • Haber-Bosch Process • Creates 500 million tons artificial fertilizer/year • High pressure and intense heat (750-1200 degrees F) cause atmospheric Nitrogen and Hydrogen to form Ammonia (NH3) • most of its is further processed to urea and ammonium nitrate (NH4NO3).
Decomposition • Proteins made by plants and animals pass through the food web • Excretions and Dead animals get broken down by decomposing microorganisms • Creates ammonia (NH3)
Nitrification • Ammonia from decay can be taken up directly by plants but usually converted first to nitrates (NO3-) • Bacteria break down NH3 to nitrites (NO2−) and then to nitrates (NO3-).
Denitrification • Bacteria living deep in soils and aquatic • Reduce Nitrates to Nitrogen gas (N2) so it returns to the atmosphere • Can they keep up with the agricultural production?
Eutrophication • Excess Nitrates leach into ground water and get into bodies of water • Algal blooms do well with the added nutrients (sometimes toxic) • Prevent light from hitting deeper plants that produce O2, and their decomposition requires O2 use by the bacteria • Reduced O2 in the water results • Nitrates are harmful to humans and other organisms (amphibians)