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FPST 1213. Chemistry & Physics of Fire. Modified from a presentation developed by Thomas Woodford. The Basics. Heat Transfer Conduction Convection Radiation. Combustion/Fire . Combustion indicates control Internal Combustion Engine Fire is rapid combustion, often uncontrolled
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FPST 1213 Chemistry & Physics of Fire Modified from a presentation developed by Thomas Woodford
The Basics • Heat Transfer • Conduction • Convection • Radiation
Combustion/Fire • Combustion indicates control • Internal Combustion Engine • Fire is rapid combustion, often uncontrolled • Wildfires • House Fire • Camp Fire
The Fire Tetrahedron • Oxidizer • Fuel (Reducing Agent) • Heat • Chemical Chain Reaction
Chemistry of Fire • Propane: C3H8 + 5O2 3CO2 + 4H2O plus heat + light Heat of Combustion more energy stored in C3H8 then CO2 and H2O
If we give the propane-air mixture a push (ignition source) • One molecule oxidizes giving off heat • This heat gives the push to other propane molecules • Away it goes
Two types of flames • Premixed • Bunsen Burner • Diffusion • Candle flame
Pre-Mixed Flames • Fuel and Oxidizer together • Flame has a characteristic velocity • If gas mixture flows at this velocity the flame appears to stay in place • Velocity too high – Blows out • Velocity too low – Flashes back
Diffusion Flame • Fuel on one side • Oxidizer on the other • Flame is the reaction zone