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Unit Nine Review. IMF. Intermolecular forces Attractive forces between molecules The three states of matter depend on Strength of IMF relative to the amount of thermal energy Weaker IMF Gas Stronger IMF Solid or liquid. IMF. Surface tension Tendency of liquids to minimize surface area
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IMF • Intermolecular forces • Attractive forces between molecules • The three states of matter depend on • Strength of IMF relative to the amount of thermal energy • Weaker IMF • Gas • Stronger IMF • Solid or liquid
IMF • Surface tension • Tendency of liquids to minimize surface area • Stronger IMF, greater surface tension • Viscosity • Resistance of a liquid to flow • Stronger IMF, greater viscosity • Volatile • Easily evaporates • Dynamic equilibrium • Rate of condensation = rate of evaporation • Vapors condensing = liquid evaporating • Vapor pressure • Pressure exerted by a liquids vapor molecules
Phase Change • Melting • Solid to liquid • Freezing • Liquid to solid • Boiling • Liquid to gas • Condensation • Gas to liquid • Sublimation • Solid to gas • Deposition • Gas to solid • Boiling occurs throughout the liquid • Evaporation occurs only at the surface • Rate of Vaporization increases • Increase surface area • Increase temperature • Decrease strength of IMF • Vapor pressure increases • Decrease strength of IMF • Increase temperature • Make a liquid boil • Increase temperature • Decrease atm pressure (lowers bp) • Make a gas condense • Decrease temperature • Increase atm pressure
Calculations • Be able to use the • Heat of vaporization (boiling/condensing plateau) • Heat of fusion (melting/freezing plateau) • Specific Heat (slope) • q=mCΔT equations to calculate the energy required
Types of IMF • Dispersion • Temporary uneven distribution of electrons • Molar mass • Symmetry • Surface area • Dipole – Dipole • Permanent uneven distribution of electrons • Hydrogen Bonds • H bonded to N, O, or F
Solids • Molecular • Neutral corners • Low melting points • NM & NM • M & ML or ML & NM • Covalent • Neutral corners • High melting points • ML & ML • M & ML or ML & NM • Metallic • Positive ions (cations) • M & M • Ionic • Positive and negative ions (cations and anions) • M & NM
Water • Why is water unique? • Hydrate calculations (Worksheet 4)