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This chapter explores the properties of solutions, including solvent and solute, saturated and unsaturated solutions, factors affecting solubility, concentrations of solutions, and colligative properties such as boiling-point elevation and freezing-point depression.
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18.1 Properties of Solutions • Solution Formation • Solvent • This is the liquid that is doing the dissolving • Solute • This is what is being dissolved • Form a homogenous mixture
Solubility • Two liquids that dissolve in each other are said to be miscible • Immiscible liquids are insoluble in each other
Factors Affecting Solubility • Solubility increases with the increase in temperature (Easier to dissolve something when the temperature is increased) • Solubility increases with an increase in surface area (ex. CRUSHING) • Few exceptions that occur in the reverse
18.2 Concentrations of Solutions • Molarity is the concentration of moles per liters • Molarity (M) = moles of solute / liters of solution • Dilute solution contains a low concentration of solute • Concentrated solution contains a high concentration of solute
Practice Problems: • Calculate the molarity of a solution which contains 0.40 mol of C6H12O6 dissolved in 1.6 L of a solution. • What is the molarity of a solution containing 325 g of NaCl dissolved in 750. mL of solution?(1000 ml = 1L)
Do Now: • In complete sentences, describe how you would prepare 500 mL of a 1.4M solution of sodium chloride
Making Dilutions • Formula for making a dilution • C1 V1 = C2 V2 • “Stock solution” is the same as the original solution.
Example • A stock solution of HCl has a concentration of 12M. How much of the stock solution would be required to make 325 mL of a 6M solution?
Molality • Molality is another way to represent the concentration of a solution. • It is represented by a lower case m. • Molality = moles of solute/kg of solvent • Example: A 4.9m solution of NaCl is dissolved in 1000 grams of water. How many grams of NaCl is this?
Determine the molality of a NaCl solution in which 17.3 moles of solute are dissolved in 1400 grams.
In your notebook practice: A solution containing 250 grams of BaCl2is dissolved in 2000 g of water creating a solution that has a total volume of 2450 mL. Given: 1000 mL = 1L 1000 g = 1 kg Determine the molarity from the information above. Determine the molality from the information above.
18.3 Colligative Properties of Solutions • Properties that depend on the number of particles dissolved in a given mass of solvent. These properties can change depending on the solute that is dissolved. • Boiling Point Elevation • Freezing Point Depression
Boiling-Point Elevation • ∆Tb = Kb x m x i • m is the molality • i is the number of ions in solution (covalent: i = 1) • Kb is the molal boiling point elevation constant • It is dependent on the solvent
Freezing Point Depression • ∆Tf = Kf x m x i • m is the molality • i is the number of ions in solution (covalent: i = 1) • Kf is the molal freezing point constant • It is also dependent on the solvent
Example: • Determine the boiling point and freezing point of a solution in which 600 grams of MgCl2 is dissolved in 2400 grams of water. (Kb = 0.512 and Kf = 1.86)