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DOC and THMP loads from a restored wetland in the Delta. Jacob A Fleck Steven J. Deverel Roger Fujii. DWR RD1601 CALFED CBDA staff USGS staff. Wetland restoration. Many thousands acres of wetland restoration All native wetland types: Tidal, non-tidal, mudflat Benefits
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DOC and THMP loads from a restored wetland in the Delta Jacob A Fleck Steven J. Deverel Roger Fujii DWRRD1601 CALFED CBDA staff USGS staff
Wetland restoration • Many thousands acres of wetland restoration • All native wetland types: Tidal, non-tidal, mudflat • Benefits • Provide habitat for native species • Improve ecosystem function • Flood protection • Subsidence mitigation on organic soils • Engineering difficulties (deep subsidence) • Island in-fill • Setback levees • Impounded, flow-through wetlands
USGS/DWR wetland restoration demonstration project • Initially established in 1997 • Use of wetland restoration as subsidence mitigation technique on deeply subsided islands • Impounded, flow-through system • This study established in 2000 • To determine the effects that wetland restoration will have on DOC and THMP loads from subsided peat islands.
Twitchell Island • Deeply subsided • As much as 20 ft • Peat soils dominate • >10 ft remain • ~35% OM • Primarily agriculture • srsr corn • Water upwelling
Peat soil high in C Two layers Zone of drain influence Well-decomposed peat High hydraulic conductivity Deep peat Unaltered peat Low hydraulic conductivity Soils/drainage
Drinking water concern OH O= C C X n CR 3 O= C C X n HOOC O O HC Cl Cl 2 OH X Trihalomethanes HC X 3 OH OH OH Haloacetic Acids O= C O C O= O O C -OCl C COOH OH OH OH Haloketones -OBr CH2 O=C H3C C=O OH Haloacetonitriles CX3CN CH3 DOC MX Halophenols DBPs
Study design • Collect samples of surface and subsurface waters for DOC and THMFP analyses • Combine with water flux data to calculate loads
Monitoring plan • Surface inflow and outflow • Continuously monitored for water flux • Weekly sampling for DOC and THMFP • Piezometers • Sampled soil water 2x/yr for seasonal extremes in 2 depths at 3 piers • Shallow soils (0.5-2 ft) • Deep peat (8-10 ft)
Temporal trends • Surface water fluxes show strong seasonal trend • Subsurface DOC concentrations are decreasing over time in some shallow soil water (2001-2004)
Subsurface fluxes (estimated) • Seepage governed by hydraulic head • ~240 m3/day • Concentration in shallow soils declined over time • Pier H (2001) = 60 mg/L ~ 200 g/m2-yr • Pier H (2004) = 25 mg/L ~ 85 g/m2-yr • Pier K ~ 160 mg/L ~ 440 g/m2-yr
Temporal trend summary • Wetland net surface fluxes are seasonal • Higher in summer and lower in winter • Opposite trend of ag operations • Subsurface fluxes • No apparent seasonal trend (lack of data?) • Concentration (fluxes) have been decreasing over time for soils in flow path
DOC “quality”? • DOC quality differs in source of DOC and processing in the environment • We would expect ag, wetland soil, and surface water DOC to differ in quality • Food source vs drinking water problem? • Different carbon structures react differently in DBP formation • Some DOC structures are tasty some are not
Conclusions • Demo pond contributes more DOC and THMPs to Delta waters than nearby ag fields (>10x) • Most of demo pond loads derived from seepage through the shallow soils • If contribution from shallow soils minimized… • Demo pond loads would be more comparable to ag operations (DOC ~2x, THMPs ~4x) • Timing of loads would be different from ag operations (benefits?) • Demo pond surface water DOC is more reactive, but also more likely beneficial for food web (?)
Implications • Design of large-scale wetland restoration sites need to consider shallow soil contributions to drain flow • Need to consider the effect changing the DOC load timing from converted fields will have on Delta ecosystems and drinking water facilities? • Need to balance potential benefits for subsidence mitigation, habitat restoration and food web dynamics with potential threats to drinking water supply
Future and ongoing work • Twitchell South pond • Using lessons from demo ponds to monitor loads before, during, and after conversion • Expand studies to include other priorities (ie: MeHg) • Rice project • Using water management lessons to help determine BMPs for reducing DOC loads from rice fields in Delta • Compare conversion of corn fields to rice with conversion to wetland