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Introduction to Chemical Reactions and Equations. Chemical Reactions are Everywhere. Cooking. Respiration. Chemical Reactions are Everywhere. Hair Dye. Auto Fuel. What are the clues that a chemical reaction has occurred?. A gas bubbles off. A new solid material is formed (a precipitate .).
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Chemical Reactions are Everywhere Cooking Respiration
Chemical Reactions are Everywhere Hair Dye Auto Fuel
The key to chemical reactions! The Law of Conservation of Mass In a chemical reaction, no atoms are created or destroyed. The atoms in the reacting molecules simply re-arrange to form new molecules. Since atoms aren’t created or destroyed, no mass is created or destroyed either. Mass is “conserved.”
Terminology • In a chemical reaction, the materials to the left of the arrow are the reactants. Reactants are the substances that exist before a chemical change (or reaction) takes place. • Reactants are consumed in the reaction. • The arrow is like an equal sign in math. It can be read “react to produce” or “produces” or “forms”. • The materials to the right of the arrow are the products. The new substance(s) that are formed during the chemical changes. • H2O + SO3 H2SO4
Phase Notation • A chemical equation can also show the physical state of the materials in the reaction. This is done with phase notations: • (s) solid (l) liquid (g) gas • (aq) aqueous or dissolved in water • (ppt) or ( ) means “a precipitate forms” • ( ) means “a gas bubbles off” • means “is heated” • Phase notations are written to the lower right of each formula. Clues to phase notations are often given in equations written in words.
Ways to represent a chemical reaction • Word Equations: • decomposition of hydrogen peroxide • Iron + oxygen yields rust (iron (III) oxide) • Burning gas in lab – methane + oxygen
Skeleton Equations • Base equation – identifies the substances involved in the chemical reaction, but does not obey law of conservation of mass • Get the chemical formulas of reactants and products correct first. • REMEMBER, diatomic molecules • Once the substances are identified for the reaction, then add…….
Coefficients • In a chemical reaction, if more than 1 molecule of a substance reacts or is produced, the number of molecules is shown with a coefficient. • 6CO2 + 6H2O C6H12O6 + 6O2 • Coefficients multiply subscripts through the whole molecule that follows, so 6CO2 shows that there are 6 Carbon atoms and 12 Oxygen atoms.
Count the atoms, before & after 2H2 + O2 2H2O
How many? • How many of each atom are shown by 4Al2(SO4)3 • How many of each atom are shown by 3(NH4)3PO4
Example • When pellets of sodium hydroxide are dropped into an aqueous solution of iron(III) chloride, iron(III) hydroxide precipitates and sodium chloride stays dissolved. • 3NaOH(s) + FeCl3(aq) Fe(OH)3 (ppt) + 3NaCl(aq)
Example 2 0 Aluminum reacts with oxygen gas to form aluminum oxide 4 Al(s) + 3 O2(g)2 Al2O3(s)
Rules for Balancing Equations • 1) Write reactants and products • 2) Must have correct formulas • Remember the 7 diatomic molecules • Watch out especially for ionic compounds with correct charges. • 3) Count number of atoms • 4) Balance by changing the coefficients • Save Oxygen and Hydrogen usually for last • 5) Check answer • You’ll know if you made a mistake • 6) Make sure that you have the lowest ratio of coefficients
Main Ideas • Chemical Reactions are represented by Chemical Equations. • Chemical Equations are balanced to show the same number of atoms of each element on each side. • The Law of Conservation of Mass says that atoms won’t be created or destroyed in a chemical reaction. That is why you have to balance chemical equations!