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Law of Heat Exchange. “governs all thermal interactions”. Thermal Energy (Q) always flow from the higher temp. object to the lower temp. object. The higher temp. object loses TE (-Q) and the lower temp. object gains TE (+Q).
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Law of Heat Exchange “governs all thermal interactions” • Thermal Energy (Q) always flow from the higher • temp. object to the lower temp. object. The higher • temp. object loses TE (-Q) and the lower temp. object • gains TE (+Q). • The TE lost by the higher temp. object (QL) equals the • TE gained by the lower temp. object (Qg) . QL + Qg = 0
Q = mcDt remember, Dt = tf - ti QL + Qg = 0 so, mcDtL + mcDtg = 0 or, mc(tf – ti)L + mc(tf – ti)g = 0
mc = .500 kg mw = 1.00kg QL = -2000 J Qg = +2000 J Dtc = ? Dtw = ? 500. g of hot copper are placed in 1.00 L of cool water and the copper loses 2000 J of TE. What is the change in temperature of the copper and water. 1 g = 1 ml = 1 cm3 QL = mcDtc Dt = QL/mcc Dt = -2000 J/(.50 kgx 385 J/kg C) Dt = -10.4o C Qg = mcDtw Dt = Qg/mcw Dt = +2000 J/(1.00 kg x 4180 J/kg C) Dt = +.478o C
What is the final temp. of the mixture if the 500 g of copper are at 100o C and the liter of water are at 20o C? QL + Qg = 0 mcDtc + mcDtw = 0 expand “Q” mc(tf – ti)c + mc(tf – ti)w = 0 expand Dt mctfc – mctic + mctfw – mctiw = 0 distribute (tf – ti) mctfc + mctfw = mctic + mctiw get tf and ti alone tf(mcc + mcw) = mctic + mctiw tfc = tfw so factor out tf = mctic + mctiw mcc + mcw Isolate for “tf”
tf = .5kg(385J/kg C)100oC + 1kg(4180J/kg C)20oC .5kg(385J/kg C) + 1kg(4180J/kg C) Tf = 23.5o C