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Literature Report. 光电催化还原 CO2 的发展现状. Ang Li 2013.7.25. Photo-induced CO 2 Reduction with GaN Electrode in Aqueous System. Satoshi Yotsuhashi, Masahiro Deguchi, Yuji Zenitani, Reiko Hinogami, Hiroshi Hashiba, Yuka Yamada, and Kazuhiro Ohkawa. Applied Physics Express4 (2011).
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Literature Report 光电催化还原CO2的发展现状 Ang Li 2013.7.25
Photo-induced CO2Reduction with GaNElectrode in Aqueous System Satoshi Yotsuhashi, Masahiro Deguchi, Yuji Zenitani, Reiko Hinogami, Hiroshi Hashiba, Yuka Yamada, and Kazuhiro Ohkawa Applied Physics Express4 (2011)
Analysis method: Gas phase products: • H2: GC-TCD • CO, CH4: GC-FID Liquid phase products: • HCOOH: HPLC
Potential of Cu electrode: -1.07V -0.16V CO2reduction is realized without extra power input except for illumination with light.
Preliminary proposal Target: Gas phase products: H2, CO, CH4, CO2, N2 Liquid phase products: HCOOH, CH3OH Method: Gas phase products: GC Liquid phase products: GC(for HCOOH),HPLC (for CH3OH)
HPLC Different from GC: • Free of the limitation of Volatility and thermal stability • A broad range of Objects: GC—20% of Organics • HPLC—80% of Organics • Mobile phase: GC— inert gas, no interact with Component • HPLC—liquid, have interact with Component, so • the Polarity, PH value, Composition of • mobile liquid is important for Separate • Temperature and pressure: GC—add the temperature • HPLC—room temperature • high pressure, for the Narrower • peaks because of the high • viscosity
LLC LSC Different solubility in Two kinds of Solvent, just like L-L extraction.
Sliver paste Which kind? SEM? How?Spin coating? How to control the Thickness to be Uniform?