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Literature Report

Literature Report. Zhou Jingjie 2013/8/16. Intention. 2CH 3 OH + CO 2 （ CH 3 O ） 2 CO + H 2 O. The addition of DMP (2,2-二甲氧基丙烷）. The addition of DME （二甲醚）. The liquid methanol reforming. Water removal. The addition of DMP. H 2 O+(CH 3 O) 2 C(CH 3 ) 2 ↔ 2CH 3 OH + (CH 3 ) 2 CO.

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Literature Report

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  1. Literature Report Zhou Jingjie 2013/8/16

  2. Intention 2CH3OH + CO2（CH3O）2CO + H2O The addition of DMP(2,2-二甲氧基丙烷） The addition of DME（二甲醚） The liquid methanol reforming Water removal

  3. The addition of DMP H2O+(CH3O)2C(CH3)2 ↔ 2CH3OH + (CH3)2CO Catalytic and direct synthesis of dimethyl carbonate starting from carbon dioxide using CeO2-ZrO2 solid solution heterogeneous catalyst: effect of H2O removal from the reaction system--Keiichi Tomishige∗, Kimio Kunimori （2002）

  4. Result of addition of DMP T=413.5K ,P=5MPa

  5. The addition of DME CH3OCH3 ( g) +H2O ( g) ↔2CH3OH ( g) A Combined Experimental and Theoretical Study on the Hydrolysis of Dimethyl Ether over H-ZSM-5-The Journal of Physical Chemistry C

  6. The process of the DME reforming DME steam reforming : (CH3)2O + 3H2O(v)↔2CO2+6H2 △Hr0=+135 kJ/mol Water-gas shift : H2 + CO2↔H2O(v)+CO △Hr0= +41 kJ/mol Net reaction : (CH3)2O + 2H2O(v)↔CO2+5H2 + CO △Hr0=+176 kJ/mol

  7. Plot of the thermodynamic equilibrium product mole fractions of hydrogen of steam-to-carbon ratio and temperature for dimethyl ether steam reforming. DME equilibrium conversion as a function of temperature and steam-to-carbon ratio for the hydrolysis of dimethyl ether. CH3OCH3+H2O ↔2CH3OH the low temperature catalyst Thermodynamic equilibrium calculations of dimethyl ether steam reforming and dimethyl ether hydrolysis-Journal of Power Sources 152 (2005) 87–96

  8. The effective catalysts High T(>300℃） alumina zeolite Low T(<300℃） Temperature dependence of DME conversion in DME hydrolysis over various zeolites.. ZHM20 that provided a higher acid amount, corresponding to a lower Si/Al ratio, could maintain DME hydrolysis at lower temperature range. (△) ZHM20,(□) ZHM90, (○) Z5-90H, (◆) ALO8, and (- -) hydrolysis equilibrium. Influence of solid acid catalysts on steam reforming and hydrolysis of dimethyl ether for hydrogen production-Applied Catalysis A: General 304 (2006) 40–48

  9. The non-proton type zeolites (Na- or K-type) and CuFe2O4 composite catalysts was lower than that of the original H-type zeolites composites. Temperature dependence of (a) DME conversion and (b) the rate of H2 production in DME steam reforming over the composite catalysts of CuFe2O4 and various zeolites. A study of various zeolites and CuFe2O4 spinel composite catalysts in steam reforming and hydrolysis of dimethyl ether-international journal of hydrogen energy 36 ( 2011) 1433-1441

  10. catalyst= CuCl + solid acid CH3OCH3 ( g) +H2O ( g)→2CH3OH ( g) 2CH3OH ( g) + 1 /2O2 ( g) + CO ( g) →CH3O (CO) OCH3( g) +H2O ( g) The rate of the producing DMC decreases The amount of the DME hydrolysis decreases 甲醇、二甲醚共进料合成碳酸二甲酯--常雁红,韩怡卓（2000）

  11. The liquid methanol reforming CH3OH(l)+H2O↔CO2(g)+3H2(g) Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide---LETTER

  12. Thermodynamic calculations

  13. 3nm 8nm Pt-Mo(1:1)/TiO2 catalyst T=357K Mo>>Fe > Ru > Co > Ni > none>>Sn The EDS showed the existence of highly dispersed molybdenum species on the surface of TiO2.

  14. Pt-Fe(1:1)/TiO2 catalyst 3-5nm

  15. Effect of transition metal element addition upon liquid phase reforming of methanol with water over TiO2 supported Pt catalysts

  16. The Ir catalyst for reforming

  17. Nano-spot EDS measurements revealed that the atomic ratio of Re/Ir is higher inthe elliptical particles than the spherical one. For the 5wt% Ir–Re(1:1)/SiO2 sample, the ratio of Ir/Re in a elliptical particle is 0.85,although the ratio is 0.40 in a spherical particle. This result confirms that the elliptical particles are composed of Ir–Re composite.

  18. Effect of the supporters The basic oxide supports improved the selectivity to CO2, whereas the acidic supports suppressed the catalytic activity and selectivity. highest rate of H2 formation; high selectivity to CO2 Catalytic activity of various supported Ir–Re catalysts for liquid phase methanol reforming with water

  19. Advantages and disadvantages

  20. Finish the experiment of the addition of DMP *adjust the reaction time and the amount of the catalyst *study the effect of different catalysts on the hydrolysis of the DMP Choose the feasible proposal from thelatter two *study the different metal in theory *make the Ir-Fe/CeO2 Work plan

  21. Thanks for Your Attention! Qs & As

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