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Starter S-73. Give the scientific name for three chemical compounds. Chemical Names and Formulas. Chapter 9. 9.1 Naming Ions. Chapter 9. 9.1 Naming Ions. Monatomic Ions – only one atom Review Cations (metals) form positive charges. 9.1 Naming Ions. Monatomic Ions – only one atom Review
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Starter S-73 Give the scientific name for three chemical compounds.
Chemical Names and Formulas Chapter 9
9.1 Naming Ions Chapter 9
9.1 Naming Ions Monatomic Ions – only one atom Review Cations (metals) form positive charges
9.1 Naming Ions Monatomic Ions – only one atom Review Group 1: +1
9.1 Naming Ions Monatomic Ions – only one atom Review Group 2: +2
8.1 Molecular Compounds 9.1 Naming Ions Some metals have more than one charge (oxidation number) They are named using the name and the charge
9.1 Naming Ions Monatomic Ions – only one atom Review Anions – negative ions
9.1 Naming Ions Monatomic Ions – only one atom Review Group 17: -1
9.1 Naming Ions Monatomic Ions – only one atom Review Group 16: -2
9.1 Naming Ions Monatomic Ions – only one atom Review Group 15: -3
9.1 Naming Ions Polyatomic Ions – a charged group of atoms bonded covalently Examples – Ammonium
9.1 Naming Ions Polyatomic Ions – a charged group of atoms bonded covalently Examples – Hydrogen Sulfate
9.1 Naming Ions Polyatomic Ions – a charged group of atoms bonded covalently Examples – Carbonate
9.1 Naming Ions See page 257 for a list of polyatomic ions. There will be a quiz.
9.2 Naming & Writing Formulas: Ionic Chapter 9
9.2 Naming & Writing Formulas: Ionic Binary Compounds – composed of two elements and can be ionic or covalently bonded For Ionic names • Write the name of the cation first • Write the name of the anion • Change the ending of the anion to -ide NaBr Sodium Br Sodium Bromine Sodium Bromide
9.2 Naming & Writing Formulas: Ionic If the compound has a metal with more than one charge, we must calculate the charge Write out the formula and the charge of the anion Calculate the total negative charge This is the total charge on the cation, so divide the charge by the number of atoms PbCl4-1 PbCl4
9.2 Naming & Writing Formulas: Ionic Name the cation Name the anion Change the ending to -ide PbCl4 Lead (IV) Cl4 Lead (IV) Chlorine Lead (IV) Chloride
9.2 Naming & Writing Formulas: Ionic Example 1: Example 2: Example 3: Example 4: Na2S Sodium S Sodium Sulfur Sodium Sulfide Copper (II) O CuO Copper (II) Oxide Copper (II) Oxygen ZnI2 Zinc I2 Zinc Iodine Zinc Iodide Iron (III) Sulfide Iron (III) Sulfur Iron (III) S3 Fe2S3
Starter S-74 Write the names of the following ionic compounds • FeCl2 • V3N4 • K2O • Cu2S • AgF
9.2 Naming & Writing Formulas: Ionic To write the formula from the name • Write the ions • Cross the values of the charges • Confirm it is the smallest ratio Nickel (III) Fluoride Ni+3 F- NiF3
9.2 Naming & Writing Formulas: Ionic Example 1: Example 2: Example 3: Example 4: Calcium Bromide Ca+2 Br- CaBr2 Pb+4 O-2 Pb2O4 PbO2 Lead (IV) Oxide Magnesium Sulfide Mg+2 S-2 Mg2S2 MgS Vanadium (V) Oxide V+5 O-2 V2O5
9.2 Naming & Writing Formulas: Ionic Polyatomic Ions – Use the same rules as other ionic compounds The endings do not change So to write the formula for • Write the formula and charge for Ammonium • Write the formula and charge for Carbonate NH4+1 Carbonate NH4+1 CO3-2 Ammonium Carbonate
9.2 Naming & Writing Formulas: Ionic Polyatomic Ions – Use the same rules as other ionic compounds The endings do not change So to write the formula for • Criss Cross • If the polyatomic ion has a subscript, parenthesis are placed around the polyatomic ion NH4+1 Carbonate NH4+1 CO3-2 NH42CO3 (NH4)2CO3 Ammonium Carbonate
9.2 Naming & Writing Formulas: Ionic Example 1 Example 2 Example 3 Example 4 Sodium Phosphate Na+ PO4-3 Na3PO4 Fe(H2PO4)3 Iron (III) Dihydrogen Phosphate Fe+3 H2PO4- (NH4)2O Ammonium Oxide NH4+ O-2 Cu(ClO4)2 Copper (II) Perchlorate Cu+2 ClO4-
9.2 Naming & Writing Formulas: Ionic So to write the name for • Name the first ion (check charges if it needs a roman numeral) • Name the second ion Ag2SO4 Silver SO4 Silver Sulfate Lead (IV) (NO3)4 Lead (IV) Nitrate Pb(NO3)4
9.2 Naming & Writing Formulas: Ionic Example 1 Example 2 Example 3 Example 4 Ammonium Dichromate (NH4)2Cr2O7 Ni2(C2O4)3 Nickel (III) Oxalate CaSiO3 Calcium Silicate Cobalt (II) Hydrogen Phosphate CoHPO4
Starter S-76 Give the names for the following • Pt(NO2)2 • Mg(ClO)2 Give the formula for the following • Cesium Carbonate • Copper (I) Suflite
Starter S-77 Name • Pb(ClO4)4 • Pb(NO3)2 Give the Formula • Iron (III) Silicate • Nickel (II) Fluoride
9.3 Naming & Writing Molecular Compounds Chapter 9
9.3 Naming & Writing Molecular Compounds Molecular Compounds (two non-metals) Prefixes are used to name the subscript in the molecular formula So to name • Never use mono on the first element • Prefix and element SiO2 Silicon O2 Silicon Dioxide
9.3 Naming & Writing Molecular Compounds Example 1 Example 2 Example 3 Example 4 Nitrogen Trichloride NCl3 Dinitrogen Tetrahydride N2H4 Cl2O7 Dichlorine Heptaoxide TetraPhosphorus Trisulfide P4S3
9.3 Naming & Writing Molecular Compounds Writing formulas invloves just writing the symbols and the prefixes • Write the first element with the proper subscript • Second element and subscript Carbon Tetrabromide C Tetrabromide CBr4
9.3 Naming & Writing Molecular Compounds Example 1 Example 2 Example 3 Example 4 P2O3 Diphosphorus Trioxide IF7 Iodine Heptafluoride NO Nitrogen Monoxide P4O6 Tetraphosphorus Hexoxide
9.4 Naming & Writing Acids Chapter 9
9.4 Naming & Writing Formulas for Acids Acid – a compound that has one or more hydrogen atoms and produces hydrogen ions (H+) in solution The basic formula is Three rules for naming • When the anion (X) does not have Oxygen in it a. The name begins with hydro b. The anion’s name ends in –ic c. And the word acid is added to the end HnX Hydro Cl Hydrochloric Hydrochloric Acid HCl
Starter S-78 Name • N2O3 • SO3 • HF Give the Formula • Dihydrogen monoxide • Carbon Monoxide
9.4 Naming & Writing Formulas for Acids 2. When the anion (X) does have Oxygen and the polyatomic ion ends in -ite a. Use the name of the anion, but change the ending to –ous b. Add the word acid Sulfurous Sulfurous Acid H2SO3
Oxygen? NO YES Hydro—ic acid Ending of Polyatomic Ion? -ate -ite --ous acid --ic acid 9.4 Naming & Writing Formulas for Acids 3. When the anion (X) does have Oxygen and the polyatomic ion ends in -ate a. Use the name of the anion, but change the ending to –ic b. Add the word acid H2SO4 Sulfuric Sulfuric Acid
9.3 Naming & Writing Molecular Compounds Example 1 Example 2 Example 3 Example 4 Chloric Acid HClO3 Hydrocyanic Acid HCN Nitric Acid HNO3 Chlorous Acid HClO2
Oxygen? NO YES Hydro—ic acid Ending of Polyatomic Ion? -ate -ite --ous acid --ic acid 9.4 Naming & Writing Formulas for Acids To write the formulas, we go backwards through our list Acids always have an H+ ion Hydro means no Oxygen – so Fluoric means Fluoride H+ Hydrofluoric Acid H+ F- HF Hydrofluoric Acid
Oxygen? NO YES Hydro—ic acid Ending of Polyatomic Ion? -ate -ite --ous acid --ic acid 9.4 Naming & Writing Formulas for Acids To write the formulas, we go backwards through our list Acids always have an H+ ion ous means the ion ended in ite, so phosphite H+ Phosphorous Acid Phosphorous Acid H+ PO3-3 H3PO3
Oxygen? NO YES Hydro—ic acid Ending of Polyatomic Ion? -ate -ite --ous acid --ic acid 9.4 Naming & Writing Formulas for Acids To write the formulas, we go backwards through our list Acids always have an H+ ion ic means the ion ended in ate, so phosphate H+ Phosphoric Acid Phosphoric Acid
9.3 Naming & Writing Molecular Compounds Example 1 Example 2 Example 3 Example 4 HI Hydroiodic Acid HC2H3O2 Acetic Acid Hypochlorous Acid HClO Carbonic Acid H2CO3
9.5 The Laws Governing Formulas and Names The Law of Definite Proportions – in any chemical compound, the masses of the elements are always in the same proportion The ratio of this molecule is always Or (Same Ratio) Carbon:Hydrogen 2.98:1:00 1:00:0.34
9.5 The Laws Governing Formulas and Names The Law of Multiple Proportions – Whenever the same two elements form multiple compounds, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers Huh? For example one compound A second compound might be The ratio of the two masses would be 5g A 10g A 2g B 2g B