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HBr , V(m+5 ) ( updated 131211; slide 8) KER spectra vs J´ and predicted KER´s ( slides 2-3) Vibrational peak assignments (?) ( slide 4) I(H + + Br (1/2)) / I(H + + Br (3/2)) vs . J´ ( slide 5)
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HBr, V(m+5) (updated 131211; slide 8) • KER spectravs J´ and predicted KER´s (slides 2-3) • Vibrationalpeakassignments(?) (slide 4) • I(H+ + Br(1/2)) / I(H+ + Br(3/2)) vs. J´ (slide 5) • I(H++Br/Br*<-HBr+/HBr+*) over I(H+ + Br(3/2)) vs. J´(slide 6) • Ref: • agust-lab-top,C:/…/PPT-131112.pptx
H+ + Br(3/2) HBr, V(m+5) H+ + Br(1/2) Predictions: Redtriangles: H+ <- HBr +blue bars: H+ + Br/Br* <- H*+Br/Br* H+ <- HBr+(v´) J´= 3 2 1 0 INCORRECT predictions KER/eV Agust,labtop,C:/…/PXP-131112.pxp ; Gr0, Lay0
I(H+ + Br(1/2)) I(H+ + Br(3/2)) J´ Agust,labtop,C:/…/PXP-131112.pxp ; Gr2, Lay2
HBr, V(m+5) H+ <- HBr+ H+ + Br(3/2) decreaseswith J´ J´= 0 1 2 3 KER/eV Agust,labtop,C:/…/PXP-131112.pxp ; Gr1, Lay1
Aboutthesplittings of thepeaks: i.e. a recoileffect agust,labtop,C:/../jcp121-9855-04.pdf
Seealso ref: https://notendur.hi.is/~agust/rannsoknir/papers/jcp127-124304-07a.pdf Page: 7: „Formation of…..“
HBr, V(m+5) H+ + Br(1/2) H+ + Br(3/2) Predictions: blue bars: H+ + Br/Br* <- H*+Br/Br* Black bars: H+ + Br- Recoil splittings Recoil splittings KER/eV Agust,labtop,C:/…/PXP-131112.pxp ; Gr0, Lay0 <= ../XLS-131113a.xlsx
I(H+<- HBr+(v+)) I(H+ + Br(3/2)) J´ https://notendur.hi.is/~agust/rannsoknir/Crete/XLS-131211.xlsx https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131211.pxp; Gr5, Lay5