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Chapter 3: Spectral lines in stars. Emission and absorption of light. Continuous spectrum (thermal, blackbody). Emission line spectrum. Independent of composition. Dependent on composition. Each element has its own unique spectrum. Absorption lines in the Sun’s spectrum.
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Emission and absorption of light Continuous spectrum (thermal, blackbody) Emission line spectrum Independent of composition Dependent on composition
Gustav Kirchhoff (1824-1887) Absorption Line Spectrum
Emission Line Spectrum • Produced by a low-density gas • depends on composition and temperature
The Balmer series for hydrogen: Visible light electrons falling to n=2 Rydberg formula (Balmer for nf = 2) : 1 / = R (1/nf2 - 1/ni2) R = Rydberg constant = 1.097 x 107 m-1
Energy levels and transitions of the many-electron atom: Sodium Quantum states of the valence electron
The Bohr Model • Classical physics predicts that the electron should spiral into the nucleus • Cannot explain emission spectra
The Bohr model: • The e- stays in certain stable orbits, emits no radiation unless it jumps to a lower level • The angular momentum of the e- is quantized • the attaction between p and e- provides the centripetal acceleration n = principal quantum number
1 q1 q2 F = r2 40 From Coulomb’s law, the force between the proton and electron is Where q1 = q2 = e for the hydrogen atom This is the centripetal force, mv2 / r
-1 e2 r 40 PE of the electron in the nth level: Un = So when the electron is in any energy level n: Bohr radius a0 = 0h2 / me2 = 5.29 x 10-11 m KE of the electron in the nth level: Kn = 1/2 mv2 Total energy En = Kn + Un = ??? Compare to Rydberg formula!
m1 m2 mr = m1 + m2 Reduced mass: the nucleus is not infinite in mass, Bohr model is off by 0.1% isotopes
Why is the emission spectrum of ionized helium similar to that of hydrogen? Because hydrogen and helium are similar chemically Because several of the energy levels of hydrogen and helium are the same Because hydrogen and helium have similar atomic masses It is a total coincidence
Energy Level Transitions • Continuum • Ionization • Differences between elements • isotopes Not Allowed Allowed
The Hertzsprung-Russell diagram plots the luminosity vs. temperature of stars Luminosity Temperature
B - V is a measure of color: the smaller B-V, the hotter the star (magnitudes, remember!)
Lines in a star’s spectrum correspond to a spectral type that reveals its temperature (Hottest) O B A F G K M (Coolest)