20 likes | 128 Views
Enhanced Optical Effects in Multi-Chromophore Metal Assemblies Theodore Gore Goodson III, University of Michigan-Ann Arbor, DMR 0802968. λ / nm. 450. 500. 550. 600. 650. 700. 750. Ru6. 310 nm. 492 nm. IVR. h ν. Pump-Probe Time Delay / ps. 572 nm. 0.006. 644 nm. Δ A. Ru. LC.
E N D
Enhanced Optical Effects in Multi-Chromophore Metal Assemblies Theodore Gore Goodson III, University of Michigan-Ann Arbor, DMR 0802968 λ / nm 450 500 550 600 650 700 750 Ru6 310 nm 492 nm IVR hν Pump-Probe Time Delay / ps 572 nm 0.006 644 nm Δ A Ru LC Fe -0.014 Yoon, Z., Newkomb, G. , Goodson , T. III ., J. Phys. Chem. 2010 ASAP on web. Ru3Fe3 CTRu CTFe CTRu LC hν D Fe Ru Ru hν hν A Fe Fe Ru Daniel C. Flynn, Guda Ramakrishna, Hai-Bo Yang, Brian H. Northrop, Peter J. Stang and Theodore Goodson, III J. Am. Chem. Soc., 2010, 132 (4), pp 1348–1358