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Metal Basicity vs Nucleophilicity and Reductivityy

Metal Basicity vs Nucleophilicity and Reductivityy. Gas-phase Basicity CH 3 -  CH 4 0 KCH 3  CH 4 20 NaCH 3  CH 4 40 LiCH 3  CH 4 60 CH 3 MgBr  CH 4 80 in K cal mol -1. Metal Effects - I.

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Metal Basicity vs Nucleophilicity and Reductivityy

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  1. Metal Basicity vs Nucleophilicity and Reductivityy • Gas-phase Basicity • CH3-  CH4 0 KCH3  CH4 20 NaCH3 CH4 40 LiCH3  CH4 60 CH3MgBr CH4 80 • in K cal mol-1

  2. Metal Effects - I

  3. Metal Effects - II

  4. Metal Effects - III

  5. Metal Acidity vs. Reactivity and Selectivity

  6. TITANIUM

  7. Cram Selectivity :

  8. Enantioselectivity :

  9. Olefination Reaction :

  10. ALUMINIUM

  11. ZINC I : Synthesis

  12. ZINCII : Use

  13. CERIUMHydride Reductions - I

  14. CERIUMHydride Reductions - II

  15. CERIUMOrganocerium Reagent

  16. SAMARIUM

  17. SAMARIUM

  18. MANGANESEOrganomanganese - I

  19. MANGANESEOrganomanganese - II

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