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myo -inositol (MI). NAD +. myo -inositol dehydrogenase IdhA (RL3622). NADH + H +. 2-keto- myo -inositol (2KMI). 2-keto-inositol dehydratase IolE (RL1493). H 2 O. 3D-(3,5/4)-trihydroxycyclohexane-1,2-dione (THcHDO) (formerly D-2,3-diketo-4-deoxy- epi -inositol). THcHDO hydrolase
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myo-inositol (MI) NAD+ myo-inositol dehydrogenase IdhA (RL3622) NADH + H+ 2-keto-myo-inositol (2KMI) 2-keto-inositol dehydratase IolE (RL1493) H2O 3D-(3,5/4)-trihydroxycyclohexane-1,2-dione (THcHDO) (formerly D-2,3-diketo-4-deoxy-epi-inositol) THcHDO hydrolase IolD (RL1494) H2O 5-deoxy-glucuronic acid (5DG) isomerase IolB (RL1492) 2-deoxy-5-keto-D-gluconic acid (DKG) DKG kinase IolC (RL1495) ATP ADP 2-deoxy-5-keto-D-gluconic acid 6-phosphate (DKGP) aldolase IolJ (?) malonic semialdehyde (MSA) dihdroxyacetone phosphate (DHAP) MSA oxidative decarboxylase IolA (RL0776) CoA NAD NADH +H+ acetyl-CoA + CO2 glyoxylate/TCA cycle