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Safe Hazardous Materials Transportation Training. Hazmat Overview. Transporting HM is serious business >13,000 chemical related deaths annually >90% of HM shipped over highways All individuals involved in any manner with HM transport are HM employees as defined in 49CFR.
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Hazmat Overview • Transporting HM is serious business • >13,000 chemical related deaths annually • >90% of HM shipped over highways • All individuals involved in any manner with HM transport are HM employees as defined in 49CFR
Hazardous Materials Table • All hazardous materials are on HM table • Alphabetical order by proper shipping name • Each HM has a unique identification number • All begin with UN (United Nations) • Table begins on approximately p.154 in HM Guide • Need product name to use HM Table
Column 1 - Symbols • (+) => Prohibits any description variation • A => Refers to air transit only • D => Refers to domestics transit only • G =>Requires one or more technical names be entered in parentheses • I => Refers to international transit only • W => Refers to water transit only
Column 2 - Proper Shipping Name • Descriptions and Proper Shipping Name • If do not have name, but have ID number - use ID Cross Reference chart on p.88 • Numbers are listed in order -- gives you proper shipping name to cross reference to HM Table
Column 3 - Hazard Class • Each HM is in a Hazard Class • Refer to p.14-15 to see the classes
Class 1 - Explosives Class 2 - Gases Class 3 - Flammable and Combustible Liquids Class 4 - Flammable Solids Class 5 - Oxidizers and Organic Peroxides Class 6 - Poisons Class 7 - Radioactive Materials Class 8 - Corrosives Class 9 - Miscellaneous ORM-D - Other Regulated Material Hazard Classes
Column 4 - Product Identification Number • Used to be NA prefixes - being fazed out • New prefix is UN - United Nations • used globally for uniform referencing • Each HM has its own unique ID#
Column 5 - Packaging Group • Refers to the least necessary packaging group required • Three categories based on degree of danger • PG I - Strongest type, any product can be packed in this type • PG II - intermediate • PG III - Only the least dangerous material may be packed in this type
Column 6 - Proper Label Code • Refers to the hazard warning labels required for the package • All HM packages are required to be labeled • Labels should be facing out when loaded on skids
Column 7 - Special Provisions • Refers to the special provisions listing that begins on page 515 • Should be checked for any special precautions or information on product
Hazardous Substances • Material including its mixtures and solutions, in a quantity, in one package, that equals or exceeds the reportable quantity listed. • Appendix A, 172.101 beginning on page 441
Hazardous Substance Cont… • If the quantity exceeds the RQ, the letters RQ must appear • Either before or after the description on the shipping papers • OR RQ can be in place of the “X” in HM column
When is Placarding Required? • Depends on TYPE and QUANTITY • TABLE 1 requires placards in any amount • refer to page 37 • TABLE 2 (page 37-38) requires placards when amount exceeds 454 kilograms, or 1,001 lbs.....
1,000 Kilogram Rule • If aggregate weight of all TABLE 2 materials exceeds 454 kg, but no one product exceeds 1,000 kg(2,205 lbs) a DANGEROUS placard can be used in lieu of the specific placards • Remember these conversions • 1,000 kg = 2,205 lbs • 454 kg = 1,001 lbs
Example Placard Problem • Trailer contains the following HM: • 2,000 lbs Class 8 Corrosives • 600 lbs Class 5.1 Oxidizer • 1,010 lbs Class 2.1 Flammable Gas • What placards would be required? + + OR
Example 2 • 3,000 lbs Class 8 Corrosive • 600 lbs Class 5 Oxidizer • 1,010 lbs Class 2.1 Flammable Gas • What placards are required? • Either specific placards for each as before, OR +
REMINDER! • TABLE 1 REQUIRES HAZARD CLASS SPECIFIC PLACARDS IN ANY AMOUNT!
Large Quantities of a Single HM • Shipments containing only one type of HM in non-bulk that are: • Each package is marked with the proper shipping name & ID# • Aggregate gross weight of the HM is 4,000KG (8,820 lbs) or more • All HM is loaded at one facility • Vehicle contains no other HM • Must have the ID# placed on each side and each end of the vehicle • Does not apply to Class 1, Class 7, or to non-bulk packages for which an ID number is not required
All HM except ORM-D requires shipping papers UN Identification Number Proper Shipping Name Hazard Class Packaging Group Quantity NEW! - First 4 entries must be in this order (IHSP) – NOTE* Voluntary compliance begins 1/1/08, mandatory compliance begins 1/1/2013 Only quantity can be abbreviated (lbs..., kg) Can be placed 1st or last Shipping Papers 10 Drums-Hydrochloric Acid/Class 8/UN1789/III/500 gal
Shipping Papers Change • A new item to watch for in the Basic Description in addition to the information on the previous slide • Must list the number and type of packages • i.e. “12 drums” or “12 boxes”, etc. • This is different than listing the quantity by mass or volume
Mixed Shipments • 3 ways to identify HM in mixed shipments • List HM first on shipping papers • Place an “X” in HM column • Use contrasting ink color
Shipping Paper Location • Within reach of the driver when restrained in seatbelt • Tabbed or on top of any other paperwork • *Should be in plain view* • When driver leaves vehicle • Left in driver’s seat, OR • Left in driver’s door pouch
Driver’s Responsibilities • Check for proper paperwork • Check for proper placards and labels • Proper Load securement • Check tires according to regulations • Know vehicle attendance requirements
Emergency Response Guide • Contains information on the following: • Fires • Leaks • Spills • First Aid • Must be in driver’s possession while transporting HM
ERG Cont... • Has 4 color coded sections • Yellow: when ID# is known • Blue: when product name is known • Orange: Emergency response info guides • Green: Isolation Distances • Note: highlighted entries are inhalation hazards, refer to the green section
Final Precautions • This training is not meant to make you a hazmat emergency responder • Things you cannot see can kill you • Things you cannot smell can kill you • Fire can be invisible • Do not take unnecessary risks that may do severe harm to yourself or others
Thank You for Attending Hazardous Materials Safety Training