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Naming Acids. Dr. Jerry E. Sipe Ivy Tech Community College. What You Need To Know. Acid nomenclature is different from other compound nomenclature Other compounds are named for their cations and their anions Acids are named for their anions… because they have a common cation: H +.
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Naming Acids Dr. Jerry E. Sipe Ivy Tech Community College
What You Need To Know • Acid nomenclature is different from other compound nomenclature • Other compounds are named for their cations and their anions • Acids are named for their anions… • because they have a common cation: H+
Classification of Acids • Classified by the number of hydrogen ions produced • Monoprotic: HCl H+ + Cl- • Diprotic: H2SO4 2 H+ + SO4-2 • Triprotic: H3PO4 3 H+ + PO4-3 • Recognizing this classification is vital when stoichiometry and/or balancing equations are required
Classification of Acids • Classified by type of anion • Binary: monatomic anion: HCl • Tertiary: polyatomic anion: H2SO4 • Recognizing this classification is vital in naming acids and writing formulas from their names
Writing Acid Formulas:Binary Acids • Formula writing begins with analyzing the key parts of the name • Binary acids are recognized by the following: • HYDROELEMENTIC CROSS MULTIPLY CHARGES H+ E-X HXE
Hydrochloric Acid Indicates a binary acid containing chlorine H+ Cl- H Cl 1 1
Writing Acid Formulas:TertiaryAcids – Names ending in “ous” • POLYATOMICSTEMOUS ACID CROSS MULTIPLY CHARGES H+ ZO-X HXZO
Nitrous Acid Indicates a polyatomic anion with lowest amount of oxygen in nitrogen series (nitrite) NO2- H+ H NO2 1 1
Writing Acid Formulas:TertiaryAcids – Names ending in “IC” • POLYATOMICSTEMIC ACID CROSS MULTIPLY CHARGES H+ ZO2-X HXZO2
Sulfuric Acid Indicates a polyatomic anion with highest amount of oxygen in sulfur series – SULFATE SO4-2 H+ SO4 H 2 1
Perchloric acid Indicates a polyatomic anion with highest amount of oxygen in chlorine series PERCHLORATE ClO4- H+ H ClO4 1 1
Hydrophosphoric Acid Indicates a binary acid containing phosphorous H+ P-3 H P 3 1
Hydroiodic Acid Indicates a binary acid containing iodine H+ I- H I 1 1
Hypochlorous Acid Indicates a polyatomic ion with the lowest level of oxygen in the chlorine series HYPOCHLORITE H+ ClO- H ClO 1 1
Naming of Acids: Formula to Name • Acid names derived from the anion • Binary acids: HYDROELEMENTIC ACID • Example: HI IODIDE ion is anion • …IDE IC • Therefore the name of the acid is • HYDROIODIC ACID
Naming of Acids: Formula to Name • Tertiary acids “ite” ending: ITE OUS • ION NAME STEMOUS ACID • Example: H3PO3; PO3-3is the phosphite ion; therefore, the name of the acid is PHOSPHOROUS ACID • Note: the “OR” in the name is added to complete the elemental name
Naming of Acids: Formula to Name • Tertiary acids “ic” ending: ATE IC • ION NAME STEMIC ACID • Example: HPO4; PO4-is phosphate ion; therefore, the name of the acid is PHOSPHORIC ACID • Note: the “OR” in the name is added to complete the elemental name
H2S Only one element (sulfur) other than hydrogen – a binary acid; therefore… Hydro sulfur ic Acid
H2SO3 Sulf ite Ion Sulfur ous Acid
HNO3 Nitr ate Ion Nitr ic Acid
HF Only one element (fluorine) other than hydrogen – a binary acid; therefore… Hydro fluor ic Acid
HClO3 Chlor ate Ion Chlor ic Acid
HIO Hypoiod ite Ion Hypoiod ous Acid