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Dry Cell Battery. Anode (-) Zn ---> Zn 2+ + 2e- Cathode (+) 2 NH 4 + + 2e- ---> 2 NH 3 + H 2. Alkaline Battery. Nearly same reactions as in common dry cell, but under basic conditions. Anode (-): Zn + 2 OH - ---> ZnO + H 2 O + 2e-
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Dry Cell Battery Anode (-) Zn ---> Zn2+ + 2e- Cathode (+) 2 NH4+ + 2e- ---> 2 NH3 + H2
Alkaline Battery Nearly same reactions as in common dry cell, but under basic conditions. Anode (-): Zn + 2 OH- ---> ZnO + H2O + 2e- Cathode (+): 2 MnO2 + H2O + 2e- ---> Mn2O3 + 2 OH-
Mercury Battery Anode: Zn is reducing agent under basic conditions Cathode: HgO + H2O + 2e- ---> Hg + 2 OH-
Lead Storage Battery Anode (-) Eo = +0.36 V Pb + HSO4- ---> PbSO4 + H+ + 2e- Cathode (+) Eo = +1.68 V PbO2 + HSO4- + 3 H+ + 2e- ---> PbSO4 + 2 H2O
Ni-Cad Battery Anode (-) Cd + 2 OH- ---> Cd(OH)2 + 2e- Cathode (+) NiO(OH) + H2O + e- ---> Ni(OH)2 + OH-
H2 as a Fuel Cars can use electricity generated by H2/O2 fuel cells. H2 carried in tanks or generated from hydrocarbons
Hydrogen—Air Fuel Cell Figure 20.9
Ballard Power Systemshttp://www.ballard.com/ A H2-based fuel cell Car using a H2 fuel cell
Hybrid fuel car, page 847