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Gabriel Performance Products

Gabriel Performance Products. Who We Are. 40 Acre Manufacturing Facility located in Ashtabula, Ohio Formerly Occidental Chemical Corporation – Designed Products Gabriel Performance Products was formed June 29, 2001 Primary Operations – Custom & Contract Manufacturing. Operating Disciplines.

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Gabriel Performance Products

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  1. Gabriel Performance Products

  2. Who We Are • 40 Acre Manufacturing Facility located in Ashtabula, Ohio • Formerly Occidental Chemical Corporation – Designed Products • Gabriel Performance Products was formed June 29, 2001 • Primary Operations – Custom & Contract Manufacturing

  3. Operating Disciplines • Quality • ISO 9001:2000 • Safety and Health • OSHA Process Safety Management • Environmental • EPA Risk Management Plan • Responsible Care • SOCMA Awardee 2005

  4. Custom Manufacturing Capabilities • Core Technology • Safe Handling of … -Epichlorohydrin (bulk) - Formaldehyde (bulk) - Hydrogen Sulfide (bulk) - Cyanide, Isocyanates - Solvents - Chlorine (bulk) • Equipment – Multi-purpose - 750 – 6,000 gal. reactor, glass lined, nickel, stainless (total of 12 reactor lines)

  5. Organization – Key Contacts • Ken Allen – President • Len Boehm – Executive Vice President • Ron Cimmino – Director, Distribution and Corporate Accounts • Kelly Lahner – Customer Service Manager/ Operations • Linda Wright – Administrative Assistant

  6. Formulation consultant - Dr. Dave Dunn • Former VP of R&D and New Business Development for Loctite • Supported a $100MM+ business • Over 35 years experience in R&D • 40+ patents and papers • 4 books • BS, MS and PhD in Chemistry

  7. Dr. Dave Dunn Member of the Editorial Advisory Board of Adhesives and Sealants Industry Magazine and writes the monthly Q & A column entitled “AskDr. Dave”

  8. Dr. Dave Dunn Helped to produce and was on-screen presenter for the History Channel’s Modern Marvels program on “Glue”

  9. Gabriel Primary Markets • Industrial Markets • Adhesives • Sealants • Coatings • Lubricants

  10. Sulfur Chemistry Expertise • Over 40 years of manufacturing experience making mercaptan resins and organo-sulfides • Safe handling of bulk hydrogen sulfide, sulfur, and sodium hydrosulfide

  11. Sulfur Chemistry Expertise • GPM-800 • Mercaptan-terminated Polymer • Used as an epoxy-curing agent • Used in thin film cures • Rapid-cure characteristics • Can be used at lower temperatures R [O(C3H6O)nCH2CHCH2SH]3 OH

  12. Mercaptan History Ashtabula Plant 1966 Capcure Launch 1986 1987 2001 1999

  13. Mercaptans Today Gabriel Performance Products is America’s original and only manufacturer of mercaptan epoxy curing agents

  14. GABRIEL GPM MERCAPTAN EPOXY HARDENERS POLY-FUNCTIONAL MERCAPTAN HARDENERS for FAST CURE of EPOXIES

  15. Polymercaptan Advantages • Rapid Cure of Epoxies • Low-Temperature Cure • Thin-Film Cure • Low Toxicity • Light Color • Excellent Adhesion • 1:1 mix ratio – not critical • Acceleration ability with other curatives e.g. amines, polyamides, anhydrides etc.

  16. Polymercaptan Applications • Consumer & Industrial Adhesives • Coatings • Sealants • Industrial Patch & Filler Kits • Floor & Flooring Repair • Electrical & Electronics • Acceleration of Other Epoxy Systems

  17. Polymercaptan Applications

  18. GPM Product Line Cognis equivalent • GPM-800Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed product • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product - • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  19. GPM Product Line Gabriel also markets GPA 30, a tertiary amine catalyst that is equivalent to Air Products Ancamine K54 or Cognis EH 30

  20. GPM-800 Product Characteristics • Uncatalyzed • Theoretical Thio Equivalent Weight – 270 • 110 Parts of GPM-800 for 100 Parts of 190 EEW Epoxy Resin • Five Minute Gel Time With Catalyst • Rapid Strength Development • Light Color / Moderate Odor • Excellent Acceleration Properties • Low Toxicity • Performance offset for Cognis’ Capcure 3-800

  21. GPM Product Line Cognis equivalent • GPM-800 Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed with GPA 30 • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product - • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  22. GPM-800 LO Product Characteristics • Same performance as GPM-800 but specially treated to reduce odor • Performance offset for Cognis’ Capcure LOF

  23. GPM Product Line Cognis equivalent • GPM-800 Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed product • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product - • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  24. GPM-888 Product Characteristics Pre-catalyzed • 8:1 blend of GPM-800: tertiary amine catalyst GPA 30 • Theoretical Thio Equivalent Weight – 190 • 100 Parts of GPM-888 for 100 Parts of 190 EEW Epoxy Resin • Five Minute Gel Time • Rapid Strength Development • Light Color / Moderate Odor • Excellent Acceleration Properties • Low Toxicity • Performance offset for Cognis’ Capcure 3830-81

  25. Five Minute Clear adhesive Resin Percent Mixed 1:1 with Hardener Percent • Epoxy resin1 78 GPM-888 98 • Epoxy resin2 20 Fumed silica 2 • Fumed silica 2 • Standard BADGE epoxy,EEW 185-190 • Aliphatic epoxy

  26. Five Minute Metallic Paste Resin Percent Mixed 1:1 with Hardener Percent Epoxy resin1 45 GPM-888 35 Barytes 20 DETDA 8 Whiting 20 Triphenyl phosphite 2 Iron oxide 14 Barytes 10 Fumed silica 1 Kaolin 6 Ca carbonate 35 TiO2 3 Fumed silica 1 1.Standard BADGE epoxy,EEW 185-190

  27. Five Minute Epoxy Putty Resin Percent Mixed 1:1 with Hardener Percent Epoxy resin1 35 GPM 888 38 Glass microspheres 10 Glass microspheres 10 Zinc sulfide 5 Powdered talc 52 Powdered talc 50 1.Standard BADGE epoxy,EEW 185-190

  28. GPM-800 or 888 Typical data/properties Resin Parts Mixed 1:1 with Hardener Parts Epoxy resin1 100 GPM-800 100 GPA-30 10 Gel time, 60gram mass 2.5 min Gel time, .015” film 5.5 min Shows relative insensitivity to mass of sample 1. Standard BADGE epoxy,EEW 185-190

  29. GPM-800 or 888 Typical data/properties Hardness, Shore D After 5 mins 18 20 mins 47 1 hr 84 24 hr 84 Shows the rapid development of properties

  30. GPM-800 or 888 Typical data/properties Lap shear strength, psi Aluminum, etched 2870 Aluminum, untreated 1845 Mild steel, sandblasted 3525 TPE polyester, abraded 147 Thermoplastic olefin, abraded 226 Shows outstanding adhesion to metals –epoxies have limited performance on plastics

  31. GPM Product Line Customized Blends Characteristics • GPM-800 Blends • Cure-Time tailored to Customer Requirements; • 40-Seconds to 30-Minutes • Special Effects • Unique Applications

  32. GPM Product Line Cognis equivalent • GPM-800 Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed product • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product - • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  33. GPM-895 FC Product Characteristics • Mix 1:1 with standard epoxy resins • Fixture times of 40 seconds • Leads to “instant epoxies”, as fast as superglue for consumer adhesives • Ideal for two-component mixing/metering equipment for assembly line use. • Fast cure results in greater productivity. • Fixture time easily modified from fast to slow Performance offset for Cognis’ Capcure 40secHV

  34. GPM Product Line Cognis equivalent • GPM-800 Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed product • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product - • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  35. GPM-890 CB and 830 CB Product Characteristics • These are pre-catalyzed custom blends designed for 90 second and 30 minute gel times respectively • These blends are unique to Gabriel with no direct offsets from competitors

  36. GPM Product Line Cognis equivalent • GPM-800 Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed product • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product- • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  37. GPM-891 FC Product Characteristics • Blend of GPM-800 and a special catalyst • Produces ultra-clear formulations • Reduced tendency to yellow • The most widely used curative in Europe for consumer epoxy adhesives Performance offset for Cognis’ Capcure 3850-101

  38. GPM Product Line Cognis equivalent • GPM-800 Capcure 3800 • 5 min. gel time uncatalyzed product • GPM-800LO Capcure LOF • Low odor version of GPM-800 • GPM-888 Capcure 3830-81 • 5 min. gel time pre-catalyzed product • GPM-895 FC • 40 sec gel time pre-catalyzed product Capcure 40 SEC HV • GPM-890 CB • 90 sec gel time pre-catalyzed product - • GPM-830 CB • 30 min. gel time pre-catalyzed product- • GPM-891 Capcure 3850-101 • 5 min. gel time non-yellowing pre-catalyzed product • GPM-845 MT Capcure WR-6 • 5 min. gel time pre-catalyzed, low viscosity, highest moisture tolerance

  39. GPM-845 MT Product Characteristics • Use at 80 Parts of GPM-845MT for 100 Parts of 190 EEW epoxy • Rapid Cures • Improved Low Temperature Cures • Rapid Thin Film Cures, even below freezing • Improved Moisture Resistance for outdoor applications • Low Viscosity allows high filler loadings • Gel Time Control by adding weak acids • Ideal for outdoor construction applications Performance offset for Cognis’ Capcure WR-6

  40. Concrete construction adhesive for low temperature applications Resin Parts Mixed 1:1 with Hardener Parts Epoxy resin1 42 GPM 845MT 85 Epoxy Novolac 45 Wollastonite 106 Epoxy diluent 13 Silica flour 10 Silane A-187 1.5 Defoamer 0.2 Wollastonite 120 Aromatic oil 7.33 Defoamer 2.0 Fumed silica 0.3 1. Standard BADGE epoxy,EEW 185-190

  41. Summary of GPM products

  42. The Gabriel Advantage • Manufactured polymercaptans and organo-sulfur compounds for over 40 years • ISO 9001:2000 quality • Can offer customized polymercaptans • Not just a raw material supplier – can offer formulation assistance • Committed to new product development to expand product line • Commitment to quality, service, and VALUE.

  43. Traditional Market Applications • Consumer adhesives • Auto aftermarket adhesives & repair compounds • Hobby & crafts adhesives and coatings • Industrial adhesives • Electrical/electronic adhesives/potting • Concrete grouts and repair compounds • Coatings

  44. Strategic Growth Plan • Markets for Growth • Road Markers / Traffic Paint • NSF Potable Water applications • Commercial Flooring – Low Odor [ 800LO] • Metal Tanks / Drums/ Rail / Bridge Coatings • Insulated Glass / Window Assembly [Polysulfide] • Electronics – Circuit Boards • Anchor Bolts / Cement • Joint Sealant Compounds • Composites – Aerospace • Composites – Industrial • Manhole Covers • Cat – Walk • Windmill Blades

  45. Reminder of Key Selling Points • GPM mercaptans: • Fast controllable curing from seconds to minutes – “dial a speed” • Modern 2 component syringes/cartridges are ideal for measuring and mixing fast systems with 1: 1 mix ratios • Low temperature cures to 16 deg F or below –most epoxies do not cure below 40 deg F • No amine “blush” or induction times • Safe to handle, e.g. NSF Standard 61 approval readily obtained • Mercaptans do not require “corrosive “labeling for shipping • Acceleration ability with other curatives

  46. Gabriel – Value Proposition “ Competitive Advantage” • Flat & responsive Management Team • Pro-active Customer Service - Kelly Lahner - Tammy Kassay • Experienced Lab/ Tech Service – Formulary Expertise - Dr. Dave Dunn • GPM – 800 Series – Complete and Diversified portfolio • In Depth Technology • Manufacturing Capability -Flexible -Global Capacity -Customization -ISO Quality Certification

  47. Gabriel – Value Proposition “ Competitive Advantage” cont’d • Consistent and Lower Color –Gardner Scale • Consistent and Lower Metals – Fe “Iron” Content -”Pinking” Phenomenon - “Blushing” • Lower Odor -Variety of masking agents • Customer Focus – Receptive to LTL custom blends • Commitment – Investment for quality and growth • Improved Adhesion Performance

  48. Gabriel Performance Products “Competitive Profile” • Cognis – Capcure Line ™-made in Spain • TORAY (Japan) - THIOL -Chemistry • LAREDO (Mexico) -modified hydrogen sulfide chemistry • ARNETTE LTD (USA) -Limited line of amines -Mercaptan Blends – select few • HUNTSMAN (USA & UK) -Mercaptan Blends – select few -”ARALDITE” ™

  49. GABEPRO – Looking Forward! • Volume has priority relative to price • Protect and Grow GPM Business • Focus on “Blends” • Customization of formulas • The original and only domestic source of Mercaptans • Have fun!

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