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Earth’s Mineral Resources. Unit 2 Sect B Environmental Chemistry. Coin-Design Competition. One requirement for the new coin is to specify the coin’s material/composition We have studied the elements Where are the elements located on Earth?
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Earth’s Mineral Resources Unit 2 Sect B Environmental Chemistry
Coin-Design Competition • One requirement for the new coin is to specify the coin’s material/composition • We have studied the elements • Where are the elements located on Earth? • First a little background about the earth’s structure
Cross Section of Earth • Earth can be divided into 3 main layers based on the materials that make up those layers • _____ -- _______ • Continental Inner • Oceanic Outer • _______ • Lithosphere • Asthenosphere • Mesosphere
Earth’s Crust • Rocky outer layer of earth is the crust • Thin compared to other layers • Mostly made of ___________ (elements silicon and oxygen), aluminum, iron, calcium
Two Types of Earth Crust • Continental crust: the rock that makes up the earth’s continents • Averages 40 km thick • Oceanic crust: rock that makes up ocean floor • Averages 7 km thick
The Mantle • Earth’s mantle: thick layer of solid rock below earth’s crust • About 2850 km thick • Mostly made of _____________ • More dense than crust • Pressure and temperature increases as you get deep inside the earth
Three Layers of Mantle • Lithosphere: ____________ part of mantle • Cool, rigid rock • Asthenosphere: middle part of mantle • Softer, weak layer, flows like taffy • Mesosphere: bottom part of mantle • Strong and stiff rock layer
The Core • The core is a large sphere of metal that occupies Earth’s center • Mostly made of _______(allows for earth’s magnetic field) • Very high pressure! Almost 3.6 million times that of earth’s surface • Temperature: about 5500oC • Outer core: liquid metal (high temp) • Inner core: solid metal (high pressure)
Study Buddy Review • What are the three main layers of the Earth? • What happens to the temperature and the pressure as you descend into the Earth? • Which metal is in the core of the Earth? Why is that important?
Sources of Elements on Earth • Atmosphere: _______________________ • Hydrosphere: water components of the earth’s surface • Lithosphere: solid part of earth
Sources of Metals • Ore: naturally occurring ______________ ______________________ and from which it is profitable to extract a metal or other material. • Minerals: naturally occurring solid compounds containing the element of interest
Study Buddy Review • What is the atmosphere? • What are minerals? • What is a metal ore?
Historic Use of Metals • Gold and silver were probably the first metals used by humans. • Found as free elements (not in ores/compounds) • Decorative • __________________
Historic Use of Metals • Copper used ~10,000 years • Bronze (alloy of _________________) developed about 3800 BC • Alloy: mixture (solution) of different metals • Iron metallurgy (extract iron from iron ore) led to Iron Age ~3000 BC
Study Buddy Review Why were the elements gold and silver probably the first used by humans? What is bronze? When was the Iron Age?
Coinage Metals • Group 11 (Cu, Ag, Au) are sometimes called the coinage metals • _______________________________________ • _______________________________________ • What results did you get for the reactivity of silver in the lab?
Reactivity of Metals Lab • In what order of reactivity did you place the metals tested in lab? • Reactivity means corrosion, formation of new compound, creation of coating, etc. • ________________________ • Is there an order of reactivities of metals in nature?
Activity Series of Metals • __________________________ metal elements ranked in order of their chemical reactivity. • Most reactive metals at the _____ of the list (Mg) • Least reactive metals at the ___________ of the list (Au) • Most reactive metals have low reactive ion in solutions (Mg2+) • Least reactive metals have highly reactive ion in solutions (Ag+)
How do Metals React? • When metals react, they lose electrons • When atoms lose electrons, they form _______________ charges • Process is called _________________ Mg (s) Mg 2+ (aq) + 2 e- • Where did the electrons go? • Electrons flow to another substance
Substances That Accept Electrons • Substances that ______electrons undergo a process called _________________: Cu 2+ (aq) + 2 e- Cu (s)
Redox Reactions • Oxidation reactions always accompany reduction reactions • Called _____________________ • OIL RIG • Oxidation is losing electrons • Reduction is gaining electrons
Redox Reactions Cu 2+ (aq) + 2 e- Cu (s) Mg (s) Mg 2+ (aq) + 2 e- Cu 2+ (aq) + Mg (s) Cu (s) • The number of electrons are always conserved ____________________________________________________________________________ • The flow of electrons can be used to create electrical energy.
Summary of Oxidation and Reduction Oxidation Reduction Gain electrons e- appear on left side of arrow in equation Charge number becomes more negative • Lose electrons • e- appear on right side of arrow in equation • Charge number becomes more positive
Oxidizing and Reducing Agents • Oxidizing Agents: are the substances that are ____________(Mg2+) • Reducing agents: are the substances that are ____________(Cu)
Other Methods for Isolating Metals • Electrometallurgy: involving the use of ________________________ to supply electrons to metal ions and reducing them • Pyrometallurgy: the treatment of metals and their ores by _________________ • Oldest ore-processing method • Hydrometallurgy: obtaining metals from their ions by treatment of ores and other metal-containing materials by ______________________________________
Study Buddy Review What is the activity series of metals? What is oxidation? What is reduction? What is an oxidizing agent?