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Chapter 8 Lecture 8.5 Hybridization

Chapter 8 Lecture 8.5 Hybridization. Section 8.3 Bonding Theories. Molecular Orbitals. a n orbital formed by the overlap of atomic orbitals Bonding orbital Can be occupied by two electrons in a covalent bond Sigma Bond Pi Bond. Sigma Bond σ. H ead-on overlap of two atomic orbitals

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Chapter 8 Lecture 8.5 Hybridization

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  1. Chapter 8Lecture 8.5 Hybridization Section 8.3 Bonding Theories

  2. Molecular Orbitals • an orbital formed by the overlap of atomic orbitals • Bonding orbital • Can be occupied by two electrons in a covalent bond • Sigma Bond • Pi Bond

  3. Sigma Bondσ • Head-on overlap of two atomic orbitals • Has axial symmetry

  4. Sigma BondσHydrogen, H2

  5. Sigma BondσFluorine, F2

  6. Pi Bondπ • Side by side overlap of two orbitals

  7. Ethene

  8. Ethyne H - C = C - H

  9. CH4

  10. Hybridizaton • The combination of orbitals

  11. sp3

  12. 8.3 Hybrid Orbitalssp2 • Hybridization Involving Double Bonds

  13. sp2Ethene, C2H4

  14. Ethene

  15. spethyne, C2H2

  16. 8.3 Hybrid Orbitals • Hybridization Involving Triple Bonds

  17. Ethyne H - C = C - H

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