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Discussion: Colligative Properties. Students will be able to: Explain how dissolved solutes affect the boiling and freezing points of solutions. Remember. Packet # 1 is due today Lab next time! . The Affect of Adding Non-volatile Solutes.
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Discussion: Colligative Properties Students will be able to: Explain how dissolved solutes affect the boiling and freezing points of solutions
Remember • Packet # 1 is due today • Lab next time!
The Affect of Adding Non-volatile Solutes • What happens to the boiling point and freezing point as solutes are added?
Will the Freezing Point Ever Go Up? • NO! Adding Solutes Will Always Make the Freezing Point Go Down
Will the Boiling Point Ever Go Down? • Sometimes. If the solute is volatile the boiling point goes down. • An example would be adding alcohol to water. The mixture will boil at a lower temperature than the pure water. • The boiling point of alcohol is only around 70oC so adding it makes the boiling point go down
Ice Will Not Melt if the Outside Temp is Lower than Zero • Since the Fp = 0 and the outside temp is -5, this ice won’t melt.
If the Outside Temperature is -5oC Salt and Ice Mixtures Can Melt • If you can add salt the mixture will not freeze until it is -10oC
Why do people add salt to roads? • Sentence #1: • Sentence #2: • Sentence #3:
Colligative Properties • What are two properties of solutions that depend on the number of dissolved particles? • Boiling Point (normally goes up) • Freezing Point
Ethylene Glycol • This is the molecule that is commonly called antifreeze. C2H6O2 • 62 grams/mol • There are two reasons it is used for antifreeze. • It has • a high boiling point • and it is very soluble in water
Antifreeze • Why is antifreeze added to cars? • The mixture of water and ethylene glycol has a higher boiling point than pure water. • The mixture of water and ethyleneglycol has a lower freezing pointthan pure water.
Molarity and molality • Molarity is the ratio of moles solute to liters of solution • Molality is the ratio of moles solute to kilograms of solvent • Notice you divide by the solvent not the solution
Calculate Molality (on discussion) • 30.0 grams of C2H6O2 (the solute) change to moles • Mixed with 30.0 grams of water (the solvent)change to Kg
What Temp Will it Freeze? • What are the two factors that influence how much it drops? • a. the molality of the solution • b. the freezing point constant of water (1.86)
How to Calculate the Boiling Point • ΔTb = m x Kb • ΔTb = m x 0.512 • ΔTb = 16.13 x 0.512 • 8.25 • Recall the temp of boiling goes up. Boiling is normally 100oC. So the temp of boiling is…… • 108.25
70 grams of water (the solvent) mixed with 30 grams of antifreeze (C2H6O2) the solute.