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IDEAL gas law. Avogadro (1776-1856) Avogadro’s Hypothesis - any sample of any gas at the same temperature and pressure will contain the same number of particles. The number of moles ( n ) is directly proportional to pressure , and volume. P 1. V 1. P 2. V 2. =. k. n. T 1.
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Avogadro (1776-1856) Avogadro’s Hypothesis - any sample of anygasat the same temperature and pressure will contain the same number of particles.
The number of moles (n) is directly proportional to pressure, and volume. P1 V1 • P2 • V2 = • k n • T1 • T2
Experiments with n, V, P, and T give Ideal gas law: R k P V n = T R= experimentally determined ideal gas constant. Value of Rdepends on the units used for pressure. L · kPa L · atm 8.314 0.0821 mol · K mol · K L · mmHg 62.4 mol · K
A steel container with a volume of 20.0 L is filled with nitrogen gas to a final pressure of 2000.0 kPa at 27.00C. How many moles of gas was used? P 2000 V (20.0) = = n R T 27°C + 273 = 300 K L · kPa 8.314 mol · K 16.0 moles n 8.314 (300)
What pressure is exerted by 640.0 g of methane (CH4) gas in a sealed 5.35L container at 27 ºC? 1 mol 16.0 g Molar mass of CH4= 16.0 g/mol (5.35) 640.0 g = 40.0 moles P V n R T = 27°C + 273 = 300 K L · kPa 8.314 mol · K • (40.0) 8.314 (300) 1.9 x 104kPa =
A child lung capacity is 2.2 L. How many grams of oxygen gas do lungs hold at a pressure of 1.00 atm and a normal body temperature of 37.00C? 32.0 g 1 mol P 101.3 V (2.2) = = n R T 37°C + 273 = 310 K 0.086 moles 8.314 (310) L · kPa Molar mass of O2= 32.0 g/mol 8.314 mol · K 0.086 mol = 2.75 g of O2