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Model structures

Model structures. (Read Roe, Chap. 5) Remember:  ( r ) ––> I ( q ) possible I ( q ) ––>  ( r ) not possible. Model structures. (Read Roe, Chap. 5) Remember:  ( r ) ––> I ( q ) possible I ( q ) ––>  ( r ) not possible I ( q ) ––>    ( r ) only

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Model structures

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  1. Model structures (Read Roe, Chap. 5) Remember: (r) ––> I (q) possible I (q) ––> (r) not possible

  2. Model structures (Read Roe, Chap. 5) Remember: (r) ––> I (q) possible I (q) ––> (r) not possible I (q) ––> (r) only Thus, use a reasonable model to fitI (q) or (r)

  3. Model structures (Read Roe, Chap. 5) Remember: (r) ––> I (q) possible I (q) ––> (r) not possible I (q) ––> (r) only Thus, use a reasonable model to fitI (q) or (r): dilute particulate system non-particulate 2-phase system soluble blend system periodic system

  4. Model structures • Use reasonable model to fitI (q) or (r): • Dilute particulate system • polymers, colloids • dilute - particulates not correlated • if particulate shape known, can calc I (q) • if particulate shape not known, can calc • radius of gyration

  5. Model structures • Use reasonable model to fitI (q) or (r): • Non-particulate 2- phase system • 2 matls irregularly mixed - no host or matrix - • crystalline & amorphous polymer phases • also, particulate system w/ no dilute species • get state of dispersion, domain size, info on • interphase boundary

  6. Model structures • Use reasonable model to fitI (q) or (r): • soluble blend system • single phase, homogeneous but disordered • two mutually soluble polymers, solvent + solute • get solution properties

  7. Model structures • Use reasonable model to fitI (q) or (r): • periodic system • crystalline matls, semi-crystalline polymers, block • copolymers, biomaterials • crystallinity poor • use same techniques as in high angle diffraction, • except structural imperfection prominent

  8. Model structures • Dilute particulate system

  9. Model structures • Dilute particulate system

  10. Model structures • Dilute particulate system

  11. Model structures • Dilute particulate system • dilute - particulates not correlated • matrix presents only uniform bkgrd • Itotal = Iindividual particle • isotropic • Radius of gyration, Rg: • Rg2= ∫r2 (r) dr/∫(r) dr • (r) = scattering length density distribution • in particle

  12. Model structures • Dilute particulate system • Radius of gyration, Rg: • Rg2= ∫r2 (r) dr/∫(r) dr • (r) = scattering length density distribution • in particle • If scattering length density is constant thru-out particle: • Rg2= (1/v)∫r2 (r) dr • (r) = shape fcn of particle; v = particle volume

  13. Model structures • Dilute particulate system • Simple shapes • For a single particle • A(q)= ∫(r) exp (-iqr) dr • I (q) = A2(q) • Average over all orientations of the particle v

  14. Model structures • Dilute particulate system • For a single particle • A(q)= ∫(r) exp (-iqr) dr • I (q) = A2(q) • Sphere: • (r) = for r ≤ R & 0 elsewhere • Then • A(q)= ∫(r) 4πr2 (sin (qr))/qr dr • A(q)=  ∫(r) 4πr sin (qr) dr • A(q)= (3v/(qR)3)(sin (qR) - qR cos (qR)) v ∞ o R o

  15. Model structures • Dilute particulate system • For a single particle • A(q)= ∫(r) exp (-iqr) dr • I (q) = A2(q) • Sphere: v

  16. Model structures • Dilute particulate system • Thin rod, length L, ∠ betwn q& rod axis =  • I(q) = (v)2(2/qL cos )2 sin2 ((qL/2)cos )

  17. Model structures • Dilute particulate system • Thin rod, length L, ∠ betwn q& rod axis =  • I(q) = (v)2(2/qL cos )2 sin2 ((qL/2)cos ) • Averaging over all orientations • I(q) = (v)2 2/qL (∫ (sin u)/u du - (1- cos qL)/ qL) qL o

  18. Model structures • Dilute particulate system • Thin disk, radius R • I(q) = (v)2 2/(qR)2 (1- (J1(2qR))/qR) 1st order Bessel fcn

  19. Model structures • Dilute particulate system • Polymer chain w/ N + 1 independent scattering "beads" • Gaussian - w/ one end of polymer chain at origin, • probability of other end at drobeys Gaussian distribution • bead volume is vu ; chain volume is v = (N + 1) vu

  20. Model structures • Dilute particulate system • Polymer chain w/ N + 1 independent scattering "beads" • Gaussian - w/ one end of polymer chain at origin, • probability of other end at drobeys Gaussian distribution • bead volume is vu ; chain volume is v = (N + 1) vu • scattering length of each bead is vu • A(q) = vu-iqrj) N+1 j=0

  21. Model structures • Dilute particulate system • Polymer chain w/ N + 1 independent scattering "beads" • Gaussian - w/ one end of polymer chain at origin, • probability of other end at drobeys Gaussian distribution • bead volume is vu ; chain volume is v = (N + 1) vu • scattering length of each bead is vu • A(q) = vu-iqrj) • I(q) = (vu)2 ∫P(r)-iqr)dr • P(r) is # bead pairs r apart N+1 j=0

  22. Model structures • Dilute particulate system • Polymer chain w/ N + 1 independent scattering "beads" • Gaussian - w/ one end of polymer chain at origin, • probability of other end at drobeys Gaussian distribution • bead volume is vu ; chain volume is v = (N + 1) vu • scattering length of each bead is vu • A(q) = vu-iqrj) • I(q) = (vu)2 ∫P(r)-iqr)dr • P(r) is # bead pairs r apart • Averaging over all such chains: • I(q) = (vu)2 ∫P(r)-iqr)dr N+1 j=0

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