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Integrated Circuit Technology. EE40 6 August 2008. Integrated Circuit Fabrication. Goal: Mass fabrication ( i.e. simultaneous fabrication) of many “chips”, each a circuit (e.g. a microprocessor or memory chip) containing millions or billions of transistors. Methods for Top Down processing:
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Integrated Circuit Technology EE40 6 August 2008
Integrated Circuit Fabrication Goal: Mass fabrication (i.e. simultaneous fabrication) of many “chips”, each a circuit (e.g. a microprocessor or memory chip) containing millions or billions of transistors • Methods for Top Down processing: • Addition of material • Subtraction of unwanted material • Thermal/Doping modification of material Analogous to making Gingerbread men… yeah.
Still in Infancy: Bottom-up Processing Cheap electronics Organic Printed Electronics – Process is serial (slow) and resolution is poor High-performance transistors Catalyzed Growth – Nanotubes/Nanowires hard to place and grow in the desired direction.
Standard Materials Set • Si substrate – selectively doped in various regions • SiO2 insulator – MOST IMPORTANT component • Polycrystalline silicon – used for the gate electrodes • Metal contacts and wiring
Si Substrates (Wafers) Why are wafers round? We pull crystalline-Si out of hot ingots, starting with a seed crystal. Crystalline-Si exhibits the best electronic properties for transistors. 300 mm Typical wafer cost: $50 (!!!) Sizes: 150 mm, 200 mm, 300 mm diameter “notch” indicates crystal orientation
Doping Makes the Silicon N-type or P-type
Adding Dopants into Si Suppose we have a wafer of Si which is p-type and we want to change the surface to n-type. The way in which this is done is by ion implantation. Dopant ions are shot out of an “ion gun” called an ion implanter, into the surface of the wafer. Eaton HE3 High-Energy Implanter, showing the ion beam hitting the end-station Typical implant energies are in the range 1-200 keV. After the ion implantation, the wafers are heated to a high temperature (~1000oC). This “annealing” step heals the damage and causes the implanted dopant atoms to move into substitutional lattice sites.
Ion Implanter translational motion e.g. AsH3 gaseous source As+, AsH+, H+, AsH2+ analyzer magnet F = q( v B ) Ion source Energy: 1 to 200 keV Dose: 1011 to1016/cm2 Inaccuracy of dose: <0.5% Nonuniformity: <1% Throughput: ~60 wafers/hr ion beam resolving aperture accelerator As+ wafer spinning wafer holder
Dopant Diffusion dopant atom concentration (logarithmic scale) as-implanted profile depth, x The implanted depth-profile of dopant atoms is peaked. In order to achieve a more uniform dopant profile, high-temperature annealing is used to diffuse the dopants Dopants can also be directly introduced into the surface of a wafer by diffusion (rather than by ion implantation) from a dopant-containing ambient or doped solid source
Annealing Fixes the damage caused by ion implantation.
Rapid Thermal Annealing (RTA) Sub-micron MOSFETs need ultra-shallow junctions (xj<50 nm) Dopant diffusion during “activation” anneal must be minimized • Short annealing time (<1 min.) at high temperature is required • Ordinary furnaces (e.g. used for thermal oxidation and CVD) heat and cool wafers at a slow rate (<50oC per minute) • Special annealing tools have been developed to enable much faster temperature ramping, and precise control of annealing time • ramp rates as fast as 200oC/second • anneal times as short as 0.5 second • typically single-wafer process chamber:
Rapid Thermal Annealing Tools Furnace RTA Lamp RTA A.T. Fiory, Proc. RTP2000 • There are 2 types of RTA systems: • Furnace-based • steady heat source + fast mechanical wafer transport • Lamp-based • stationary wafer + time-varying optical output from lamp(s)
Film Growth Allows formation of high-quality films (usually SiO2) necessary for low leakage.
Formation of Insulating Films Applied Materials low-pressure chemical-vapor deposition (CVD) chamber ASM A412 batch oxidation furnace • The favored insulator is pure silicon dioxide (SiO2). • A SiO2 film can be formed by one of two methods: • Oxidation of Si at high temperature in O2 or steam ambient • Deposition of a silicon dioxide film
Thermal Oxidation oxide thickness time, t or • Temperature range: • 700oC to 1100oC • Process: • O2 or H2O diffuses through SiO2 and reacts with Si at the interface to form more SiO2 • 1 mm of SiO2 formed consumes ~0.5 mm of Si “wet” oxidation “dry” oxidation
Example: Thermal Oxidation of Silicon 99 mm thick Si, with 1 mm SiO2 all around total thickness = 101 mm 101mm 99mm Silicon wafer, 100 mm thick Thermal oxidation grows SiO2 on Si, but it consumes Si, so the wafer gets thinner. Suppose we grow 1 mm of oxide:
Oxidation Rate Dependence on Thickness Note the 0.04mm step in the Si surface! SiO2 thickness = 1.02 mm SiO2 thickness = 0.1 mm SiO2 thickness = 1 mm Si • The thermal oxidation rate slows with oxide thickness. Consider a Si wafer with a patterned oxide layer: Now suppose we grow 0.1 mm of SiO2:
Selective Oxidation Techniques Window Oxidation Local Oxidation (LOCOS)
Deposition Allows you to put down conformal films that cannot be grown from the substrate.
Chemical Vapor Deposition (CVD) of SiO2 or “LTO” “TEOS” • Temperature range: • 350oC to 450oC for silane • ~700oC for TEOS • Process: • Precursor gases dissociate at the wafer surface to form SiO2 • No Si on the wafer surface is consumed • Film thickness is controlled by the deposition time oxide thickness time, t
Conformality • CVD Properties: • Can be deposited on top of anything. • Can follow ups & downs (topography) of pre-existing layers
Lithographic Patterning Film-camera-like process that lets you define shapes in your thin films.
Lithography refers to the process of transferring a pattern to the surface of the wafer Equipment, materials, and processes needed: A mask (for each layer to be patterned) with the desired pattern A light-sensitive material (called photoresist) covering the wafer so as to receive the pattern A light source and method of projecting the image of the mask onto the photoresist (“printer” or “projection stepper” or “projection scanner”) A method of “developing” the photoresist, that is selectively removing it from the regions where it was exposed Patterning the Layers oxidation deposition ion implantation etching lithography Planar processing consists of a sequence of additive and subtractive steps with lateral patterning
A glass mask with a black/clear pattern is used to expose a wafer coated with ~1 m thick photoresist Photoresist Exposure Image of mask appears here (3 dark areas, 4 light areas) UV light Mask Lens Mask image is demagnified by nX photoresist Si wafer “10X stepper” “4X stepper” “1X stepper” Areas exposed to UV light are susceptible to chemical removal
Exposure using “Stepper” Tool field size increases with technology generation scribe line 1 2 wafer images Translational motion
Photoresist Development photoresist Exposed areas of Developed photoresist Solutions with high pH dissolve the areas which were exposed to UV light; unexposed areas are not dissolved
Lithography Example • Mask pattern (on glass plate) A A B B (A-A and B-B) Look at cuts (cross sections) at various planes
“A-A” Cross-Section mask pattern resist 0 0 1 1 2 2 3 3 4 4 5 5 m m [ [ m] m] x x resist after development 0 1 2 3 4 5 m [ m] x The resist is exposed in the ranges 0 < x < 2 m & 3 < x < 5 m: The resist will dissolve in high pH solutions wherever it was exposed:
Pattern Transfer by Etching We have exposed mask pattern, and developed the resist photoresist First: pattern photoresist Si oxide etchant … photoresist is resistant. SiO 2 Next: Etch oxide etch stops on silicon (“selective etchant”) Last: strip resist only resist is attacked In order to transfer the photoresist pattern to an underlying film, we need a “subtractive” process that removes the film, ideally with minimal change in the pattern and with minimal removal of the underlying material(s) • Selective etch processes (using plasma or aqueous chemistry) have been developed for most IC materials Jargon for this entire sequence of process steps: “pattern using XX mask”
Photolithography quartz plate chromium • 2 types of photoresist: • positive tone: • portion exposed to light will be dissolved in developer solution • negative tone: • portion exposed to light will NOT be dissolved in developer solution from Atlas of IC Technologies by W. Maly
Projection Printing Considerations Intel’s Lithography Roadmap minimum feature size lm: Small lm is desired!
Depth of Focus depth of focus Dz : Large Dz is desirable.
Etching Remove material that you don’t want
Etching: Ion vs. Wet from Atlas of IC Technologies by W. Maly • better etch selectivity • better control of etched feature sizes
RIE-based Stringers / Spacers Leftover material must be removed by overetching
Example Process Flow CMOS Technology
CMOS Technology oxide p+ p+ p-well n+ n+ n-type Si • Challenge: Build both NMOS & PMOS transistors • on a single silicon chip • NMOSFETs need a p-type substrate • PMOSFETs need an n-type substrate • Requires extra process steps!
Conceptual CMOS Process Flow oxide p+ p+ n+ n+ n-type wafer *Create “p-well” p-well n-type Si Grow thick oxide *Remove thick oxide in transistor areas (“active region”) Grow gate oxide Deposit & *pattern poly-Si gate electrodes Grow thick oxide *Remove thick oxide in transistor areas (“active region”) *Dope n channel source and drains (need to protect PMOS areas) *Dope p-channel source and drains (need to protect NMOS areas) Deposit insulating layer (oxide) *Open contact holes Deposit and *pattern metal interconnects • At least 3 more masks, as compared to NMOS process
Additional Process Steps Required for CMOS Cross-sectional view of wafer Top view of p-well mask (dark field) boron SiO2 n-type Si 1. Well Formation p-well • Before transistor fabrication, we must perform the following process steps: • grow oxide layer; pattern oxide using p-well mask • implant phosphorus; anneal to form deep p-type regions
2. Masking the Source/Drain Implants “Select p-channel” “Select n-channel” boron photoresist oxide p+ p+ p-well n+ n+ n-type Si We must protect the n-channel devices during the boron implantation step, and We must protect the p-channel devices during the arsenic implantation step Example: Select p-channel
Forming Body Contacts oxide p+ p+ p-well n+ n+ n+ p+ n-type Si Modify oxide mask and “select” masks: Open holes in original oxide layer, for body contacts Include openings in select masks, to dope these regions
Select Masks N-select: oxide p-well n+ n+ n+ n-type Si P-select: oxide p+ p+ p-well n+ n+ n+ p+ n-type Si
Example MEMS Flow Micro Electro Mechanical Systems
MEMS Switch Source Drain Gate(s) Drain • Contact Areas: 0.4x0.4 um2 to 8x8 um2 • Devices from 50 um to 250 um long
Process Flow Elec0 Layer Isolation Si Substrate Pattern Elec0 Main Sacrificial (LTO) Dimple hole Pre-alignment Isolation Growth 6000A Low Temp Oxide 1000A Stoichiometric Silicon Nitride Poly 0 Deposition Poly 0 Formation RIE to isolation w/ overetch Main Sacrificial Deposition 5500A Low Temp Oxide Dimple Formation DRIE to Isolation or timed DRIE
Fine refill sacrificial (HTO) Anchor holes Elec1 Layer Sacrificial Release Process Flow Fine Sacrificial Deposition 650A High Temp Oxide Anchor Formation DRIE to isolation layer Poly 1 Deposition 5500A @ 615C n-doped Poly 1 Formation RIE etch to Main Sac Sacrificial Release HF:HCl 20’ then critical pt. dry Process Finished