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5.8 Acid Deposition (Rain). The pH Scale…What is acidic?. Acid Deposition (Process). Chemistry of acidified precipitations. Acid deposition can be either wet or dry: Wet deposition - acidic rain, snow, or other precipitation
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Chemistry of acidified precipitations • Acid deposition can be either wet or dry: • Wet deposition - acidic rain, snow, or other precipitation • Dry deposition - acidic gas or dry particles, not mixed with water • Pollutants can be classified as either primary or secondary: • Primary pollutants - those directly emitted by a factory or automobile • SO2 - sulfur dioxide • NO and NO2, usually identified as NOx
Chemistry Cont. • Secondary pollutants - primary pollutants react with other substances in the atmosphere and create different pollutants • H2SO3 - sulfurous acid • H2SO4 - sulfuric acid • HNO3 - nitric acid
Effects of acid deposition on environment • Direct effects (Know 1): • Inhibits embryonic development of fish • Chlorophyll loss & yellowing of tree leaves and buds → diminished growth • Thinning of cuticle (the waxy coating on needles) • Symbiotic root microbes killed (i.e. Rhizobium spp. and other beneficial fungi) • Toxic effects (Know 1): • Aluminum (Al) leaches out of soil into streams • Al disrupts salt, water, and oxygen regulating mechanisms in fish • Al can also adhere to fish gills, causing suffocation • Lichens sensitive to SO2 gases and used as indicator species
Effects of acid deposition on environment • Nutrient effects (Know 1): • Soil particles can’t retain Ca, Mg, K, and other nutrients in acidic environment, so those nutrients are leached out of soil and not available to trees • Dissolved Al ions damage root hairs (the smallest roots, which are the most effective at absorbing nutrients), so the trees are unable to absorb as many nutrients • N-fixing bacteria don’t function as well, so less N is added to soil matrix
Acid deposition is regional • Acid precipitation falls back to Earth rather than entering stratospheric jet stream • Most areas are downwind of pollution sources • Canadian forests damaged by coal-fired power plants in USA • Scandinavian and German forests damaged by British coal plants
Pollution management strategies for acid deposition • See Table 15.7 on p.298 of the IB ESS 2010 Course Companion • Replace • Switch to renewable energy sources (reduce fossil fuel use) • Increase energy efficiency (better light bulbs and appliances) • More public transportation (fewer automobiles on the road) • Use low-sulfur fuels • Regulate • Install ‘scrubbers’ on smokestacks of coal-fired power plants to remove SO2 • Catalytic converters installed on automobiles (required by law in the US, Canada, and Europe)
Management cont. • Restore • Add lime to acidified lakes and streams • Using limestone or calcium chloride (CaCO3) can neutralize (buffer) the impact of acids. • Freshwater ecosystems much more vulnerable • Expensive and hard to determine how much to add