Chapter 10 Alkanes and Aromatic Hydrocarbons

1. Chapter 10Alkanes and Aromatic Hydrocarbons Cycloalkanes Aromatic Hydrocarbons Timberlake LecturePLUS 1999

2. Cycloalkanes Cyclopropane CH2 CH2 CH2 Cyclobutane CH2 CH2 CH2 CH2 Timberlake LecturePLUS 1999

3. More Cycloalkanes Cyclopentane CH2 CH2 CH2 CH2 CH2 Cyclohexane CH2 CH2 CH2 CH2 CH2 CH2 Timberlake LecturePLUS 1999

4. Naming Cycloalkanes with Side Groups Number of Naming side groups One Side group name goes in front of the cycloalkane name. Two Number the ring in the direction that gives the lowest numbers to the side groups. Timberlake LecturePLUS 1999

5. Cycloalkanes with Side Groups Timberlake LecturePLUS 1999

6. Learning Check Alk8 Timberlake LecturePLUS 1999

7. Solution Alk8 Timberlake LecturePLUS 1999

8. Aromatic Compounds • Aromatic compounds contain benzene. • Benzene C6H6 has 6 C atoms and 6 H Atoms • Two possible ring structures show benzene. Timberlake LecturePLUS 1999

9. Benzene Structure The structures for benzene are also written as one formula with a circle within the ring to represented the alternating double bonds. Benzene structure Timberlake LecturePLUS 1999

10. Aromatic Compounds in Nature and Health Many aromatic compounds are common in nature and in medicine. Timberlake LecturePLUS 1999

11. Naming Aromatic Compounds Aromatic compounds are named with benzene as the parent chain. One side group is named in front of the name benzene. methylbenzene chlorobenzene Timberlake LecturePLUS 1999

12. Naming Aromatic Compounds When two groups are attached to benzene, the ring is numbered to give the lower numbers to the side groups. The prefixes ortho (1,2), meta (1,3-) and para (1,4-) arealso used. Timberlake LecturePLUS 1999

13. Some Common Names Some substituted benzene rings also use a common name. Then naming with additional more side groups uses the ortho-, meta-, para- system. Timberlake LecturePLUS 1999

14. Learning Check Alk9 Select the names for each structure: 1. Chlorocyclohexane 2. Chlorobenzene 3. 1-chlorobenzene 1. Meta-methyltoluene 2. Meta-dimethylbenzene 3. 1,3-dimethylbenzene Timberlake LecturePLUS 1999

15. Solution Alk9 Select the names for each structure: 2. Chlorobenzene 1. Meta-methyltoluene 2. Meta-dimethylbenzene 3. 1,3-dimethylbenzene Timberlake LecturePLUS 1999

16. Learning Check Alk10 Write the structural formulas for each of the following: A. 1,3-dichlorobenzene B. Ortho-chlorotoluene Timberlake LecturePLUS 1999

17. Solution Alk10 Write the structural formulas for each of the following: A. 1,3-dichlorobenzene B. Ortho-chlorotoluene Timberlake LecturePLUS 1999

18. Learning Check Alk11 Identify the organic family for each: Timberlake LecturePLUS 1999

19. Solution Alk11 Identify the organic family for each: alkane cycloalkane aromatic Timberlake LecturePLUS 1999

20. Fused Benzene Rings Timberlake LecturePLUS 1999

21. Carcinogens • Fused ring of benzene cause cancer • Contain four or more fused rings • Present in tobacco smoke, auto exhaust, and burned food • The more a person smokes, the greater the risk of developing cancer Timberlake LecturePLUS 1999