60 likes | 179 Views
Titration. A lab technique to determine the molarity of a compound. Basic premise…. A measured volume of a solution of unknown molarity is put into a flask Another chemical of known concentration is slowly dripped from a buret into the unknown and a reaction ensues
E N D
Titration A lab technique to determine the molarity of a compound
Basic premise… • A measured volume of a solution of unknown molarity is put into a flask • Another chemical of known concentration is slowly dripped from a buret into the unknown and a reaction ensues • The reaction proceeds until it is indicated the reaction has reached completion • Using stoichiometry, the molarity of the unknown is ascertained
indicator • Usually, visual indication that the reaction has reached completion is used • A chemical indicator is one that changes color when the reaction has reached completion, known as the “end point” • For tomorrow: SCN-(aq) + Fe3+ (aq) Fe(SCN)2+(aq) (dark red)
Tomorrow’s process… (1) A saturated solution of AgC2H3O2 is used: AgC2H3O2(s) Ag+(aq) + C2H3O2-(aq) - The solution has Ag+(aq) and C2H3O2-(aq) in equal amounts dissolved in the water (2) Ag+(aq) + SCN-(aq) AgSCN(s) (“beige” solid) Once all the Ag+ in the solution is precipitated away as AgSCN… (3) Excess SCN-(aq) + Fe3+ (aq) Fe(SCN)2+(aq)
Ksp lab calculations • Read the volume of 0.033M SCN- dripped in off of the buret M x L = moles of SCN- • Because in balanced equation (2) the coefficients of SCN- and Ag+ are the same, the moles of Ag+ = the moles of SCN- • Knowing the volume of the sample of Ag+ that was titrated… [Ag+] = moles/L • Knowing that [Ag+] = [C2H3O2-] in the original saturated solution, calculate the Ksp of AgC2H3O2