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Chapter 28 The Atom. Objectives. 28.1 Explain the structure of the atom 28.1 Distinguish continuous spectra from a line spectra 28.1 Contrast emission and absorption spectra 28.1 Solve problems using the orbital radius and energy level equations. Objectives.
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Objectives • 28.1Explain the structure of the atom • 28.1 Distinguish continuous spectra from a line spectra • 28.1 Contrast emission and absorption spectra • 28.1 Solve problems using the orbital radius and energy level equations
Objectives • 28.2Describe the shortcomings of the Bohr model of the atom • 28.2 Describe the quantum model of the atom • 28.2 Explain how a laser works and describe properties of laser light
Different Models of the Atom • Dalton: Billiard Ball • Indivisable • J.J. Thomson • Plum Pudding Model • Rutherford • The Nuclear Model (Positive nucleus with orbiting electrons) • Others have built on this model
Some Terms • Alpha Particle: Helium Particle with a positive charge • Emission Spectrum: Wavelengths emitted by an atom is called its • Absorption Spectrum: Same idea, but what wavelengths are absorbed • Spectroscope: Used to determine the wavelengths of visible light given off
Continuous Spectrum produced by having very hot objects • A theoretical black body produces a continuous spectrum
Spectroscopy: Identifying elements by their emission spectrum or absorption spectrum
Rutherford vs Bohr • Rutherford: Electrons orbit like a planet orbits a star (Planetary model of the atom) • Issues: Falling into nucleus, radiating all wavelengths
Bohr Model • Energy Quantized: Electrons only fall when giving off energy • Falls and jumps correspond to certain energies
Terms • Energy Levels: Refers to the orbital's around the nucleus (Noted as n = 1, n = 2). Also called the Quantum Numbers • Ground State: When an electron has the lowest energy level allowed • Excited State: When an electron has absorbed energy and has moved to a higher orbital. Don’t last long (nanoseconds) at the level before falling
From Last Chapter • hf (energy emitted) = Eexcited – Eground
What wavelength of light is required to make hydrogen’s electron jump from n = 1 to • N = 2 • N = 3 • N = 4
Elements beyond Hydrogen • Require different amounts of ionization energy (Graph shows outside electron) • Top Right
Atom Size • Large = More Lines • Uranium on Bottom • Hydrogen on Top
Molecules verse Atoms • Would also have a much larger range of emission lines and spectra
How many eV’s required for Helium’s 588nm emission? How many eV’s required for Heliums 402nm emission?
How much energy between shells? • Follows (1/n2) • If the n = 1 is equal to – 16 eV, how many eV of energy does a • N = 2 electron have? • - 16 eV x (1/22) = - 4 eV • N = 4 electron have? • How much energy is released going from N = 4 to N = 2? What wavelength is that?
Back to Waves • Electron Cloud: Represents a high (90%) probability of finding an electron • Quantum Mechanics: The Study of the properties of matter using its wave properties • Coherent Light: When waves of light are in sync with one another, maxima and minima lining up
Lasers • Create Coherent Light by Stimulated Emission • An electron in an excited state hit by a photon will fall releasing light in phase with the light that hit it